- 學位論文
開發快速螢光淬滅型高分子探針於純水中檢測金屬離子
A Rapid On-Off Fluorescent Polymer Probe for Detection of Metal ion in Pure Water
摘要
首先合成雙胺單體N-(4- (4-([2,2':6',2'-terpyridin]-4'-yl)phenoxy)phenyl)-N- (4-aminophenyl )benzene-1,4-diamine後與二酸單體聚合成聚醯胺，並探討其熱性質及溶解性。 本研究合成之單體含有三苯胺可以增加單體溶解性，而三吡啶具有三牙配位基可以抓取金屬離子，利用3,6,9-trioxaundecanedioic acid單體增加溶解性，單體主結構聚合物較易溶於水中或有機溶劑中，在三吡啶抓取金屬離子後降低溶解性，使聚合物在水中沉澱，可以將其應用在廢水處理的重金屬回收。
並列摘要
A series of novel polyamides containing terpyridine and triphenylamine moieties were successfully synthesized. First N-(4-(4-([2,2':6',2'-terpyridin]- 4'-yl)phenoxy)phenyl)-N-(4-aminophenyl)benzene-1,4 -diamine monomer was prepared and subsequently polymerized with dicarboxylic acids to obtain polyamides. Then, the thermal properties and solubility of the polyamides were investigated and discussed. The presence of triphenylamine and 3,6,9-trioxaundecanedioic acid moieties could provide high solubility to the polymers. Furthermore, the synthesized polymers have the ability to chelate with metal ions ascribed to the presence of terpyridine moieties. The polymer dissolving in both aqueous and organic solvent begin to precipitate the metal ions upon chelation and therefore the polymer could be applicable in the recovery of heavy metals in waste water treatments.
參考文獻
延伸閱讀
- 陳世杰（2019）。結合螢光金奈米團簇與微流體紙張平臺應用於水中汞離子檢測〔碩士論文，國立臺灣大學〕。華藝線上圖書館。https://doi.org/10.6342/NTU201902764
- 蔡春鴻、葉宗洸、鄭宇翔（2003）。高溫注氫純水環境下採行抑制性被覆304不銹鋼之腐蝕行為研究。防蝕工程，17(4)，331-340。https://doi.org/10.6376/JCCE.200312.0331
- 劉于琳（2021）。以溫度、溶劑調控製備鋅金屬有機框架化合物：合成、結構鑑定、氣體吸附與氣相碘分子、酚類化合物、硝基化合物及金屬離子之螢光感測〔碩士論文，國立暨南國際大學〕。華藝線上圖書館。https://doi.org/10.6837/ncnu202100189
- 李榮華（2004）。Olefin Polymerization and Fluorescent Properties of Conjugated Polymers in Confined Space〔博士論文，國立臺灣大學〕。華藝線上圖書館。https://doi.org/10.6342/NTU.2004.01206
- 朱玄之（2011）。Synthesis of Fluorescent Conjugated Polymers for the Applications of Surface-Modified Surfactant and Chemosensor Materials〔博士論文，國立交通大學〕。華藝線上圖書館。https://doi.org/10.6842/NCTU.2011.01010