親電性環化方法在多芳香環合成上的應用

Synthesis of Poly-Aromatic Hydrocarbons by Electrophilic Cyclization

王振儀(Cheng-I Wang)

指導教授 ： 劉瑞雄

國立清華大學/理學院/化學系/碩士(2006年)

摘要

無資料

關鍵字

親電性環化反應 ； 多芳香環

並列摘要

The dissertation discusses the synthesis of poly-aromatic hydrocarbons through electrophilic cyclization using ICl complex. We have succeeded in using this method to synthesize spiro[4,5]trienone as well as the phenanthrene derivatives. Under this foundation, we design a set of simple synthesis procedure to synthesize the dibenzo[g,p]crysene derivatives. This process requires a few steps and with excellent yields.
We also investigated on the physical properties of these dibenzo[g,p]crysene derivatives, which includs UV, PL, CV, and quantum efficiency. We found the replacement of functional groups has shown effect on the physical features. Furthermore, this present work may focus on changing different functional groups, we could apply these materials in industries.

並列關鍵字

electrophilic cyclization ； poly aromatic hydrocarbons

參考文獻

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