Taiwan has long suffered from the highly rate of occupational accidents occurrence. To reduce the occurrence rate of occupational accidents, the government has enacted of labor safety and hygiene law and labor inspection law. Notwithstanding the fact that the lows have been implemented and revised with good rewards, the occurrence rate of occupational accidents of Taiwan is still levitating higher than those of many advanced countries in the world. One of the principal causes is the lack of the concept of safe management. The purpose of this research is to introduce the conditions of occupational accident statistic mechanisms first. Then the direct cause of occupational accidents will be investigated. Finally, the safe culture of enterprise will be established by using Behavior Modification Technique. Moreover, the safety management and education will also be suggested to the industries as reference.