In this thesis, we have presented a chemical process design and integration for the recovery and utilization of carbon dioxide. Essentially, it consists of three processes: (1) recovery and utilization of carbon dioxide and conversion to the making of synthesis gas; (2) methanol production from the syngas, and (3) production of gasoline from methanol. In the study, we have also carried out a pinch analysis and heat exchanger network synthesis for the “production of gasoline from methanol”. At last, we have compared the energy consumption and capital costs of the process with/without heat integration and selected the optimal case. Two kinds of software were utilized in the research—Aspen Plus and SuperTarget. The former was used for the process synthesis, design, and simulation; the latter was used to carry out the pinch analysis and the synthesis of heat exchanger network.