Title

原子轉移自由基聚合反應合成聚偏二氟乙烯接枝聚甲基丙烯酸甲酯之接枝共聚物(PVDF-g-PMMA)及其物性與掺合薄膜的探討

Translated Titles

Synthesis of PVDF-g-PMMA through atom transfer radical polymerization and its physical properties and nanoporous membranes

DOI

10.6846/TKU.2007.01046

Authors

陳怡凱

Key Words

原子轉移自由基聚合法 ; 接枝共聚物 ; 薄膜 ; ATRP ; graft copolymer ; nanoporous membranes

PublicationName

淡江大學化學工程與材料工程學系碩士班學位論文

Volume or Term/Year and Month of Publication

2007年

Academic Degree Category

碩士

Advisor

林達鎔

Content Language

繁體中文

Chinese Abstract

本實驗以原子轉移自由基聚合法 (Atom Transfer Radical Polymerization,ATRP)合成聚偏二氟乙烯(Polyvinylidene fluoride, PVDF)與甲基丙烯酸甲酯(Methyl methacrylate , PMMA)之接枝共聚物(PVDF-g-PMMA)。利用紫外光-可見光吸收光譜儀(UV-Visible),探討不同變因對於觸媒系統的影響。合成後的產物以傅利葉紅外線光譜儀(FTIR)與核磁共振光譜儀(NMR)證明接枝共聚物的合成。將此接枝共聚物混掺PMMA後利用乾式成膜法製備薄膜,以熱重損失分析儀(TGA)及微分掃瞄熱分析儀(DSC)測量接枝混掺膜之熱性質的變化。進一步以索式萃取法製備多孔性薄膜後,以廣角X光繞射儀(XRD)、小角度X光散射儀(SAXS)與場發射電子顯微鏡(FESEM)探討薄膜的結構與物性。

English Abstract

The present research utilized PVDF and PMMA to synthesize graft copolymer by the method of atom transfer radical polymerization. Utilize ultraviolet visible spectrocomparator (UV-Visible) to characterize catalyst. The chemical structure and composition of graft copolymers was confirmed by FT-IR and NMR. The physical properties of graft copolymer were studied by using TGA, DSC, XRD, SAXS, FE-SEM.

Topic Category 工學院 > 化學工程與材料工程學系碩士班
工程學 > 工程學總論
工程學 > 化學工業
Reference
  1. 3.D. C. BASSETT, “Developments in crystalline polymers- 1”, London, 1982
    連結:
  2. 5.L. H. Sperling, “Introduction to Physical Polymer Science”, John Wiley & Sons, 2005, p.66
    連結:
  3. 8.Gould, Edwin S., “Inorganic reactions and structure”, p.163~167.
    連結:
  4. 12.Hanley K J, Lodge T P, Huang C I. Macromolecules, 2000, 33:5918
    連結:
  5. 13.Stupp S I, et al. Science, 1997, 276:384
    連結:
  6. 14.George Odian, “Principles of Polymerization”, Fourth Edition, New York. 2004
    連結:
  7. 15.By Seung Su Kim,Jae Chun Hyun, “drying of coated film”, 1999,P.386~417
    連結:
  8. 18.Robert M. Silverstein, “Spectrometric identification of oganic compounds”, Hoboken, N.J. :John Wiley & Sons,c2005. p305
    連結:
  9. 19.George Socrates, “Infrared and raman characteristic group frequencies”
    連結:
  10. 20.T. Hatakeyama and Zhenhai Liu, “Handbook of thermal analysis”.
    連結:
  11. 22.Dawa Shen, Yong Huang, D. Shen, Y. Huang ,Polymer 45 (2004) 7091–7097
    連結:
  12. 1.蔡信行,聚合物化學,文京圖書公司,民國67
  13. 2.J. F. Hester, P. Banerjee, Y.Y. Won, A. Akthakul, M. H. Acar, and A. M. Mayes, Macromolecules 2002, 35, 7652-7661
  14. 4.J. A. Brydson,范啟明,塑膠材料,大中國圖書公司,民國78
  15. 6.T. E. Patten and K. Matyjaszewski, Adv. Mat., 10, No.12, 901 (1998).
  16. 7.Tomislav Pintauer, Jian Qiu, Guido Kickelbick, and Krzyszt of Matyjaszewski*, Inorg. Chem. 2001, 40, 2818-2824.
  17. 9.Johnson B J S, Wolf J H, Zalusky A S, Hillmyer M A. Chem Mater, 2004, 16: 2909.
  18. 10.汪信, 劉孝??, 奈米材料化學,五南,2001,P.318
  19. 11.Lindoy, Leonard F.,”Self-assembly in supramolecular systems”, Royal Society of Chemistry, 2000, P.1~18
  20. 16.郭文正, 曾添文,薄膜分離,高立圖書公司, 民國77
  21. 17.趙敏勳, 儀器分析,全威圖書,民國86
  22. 21.Hugo E. Gottlieb,* Vadim Kotlyar, and Abraham Nudelman, J. Org. Chem. 1997, 62, 7512-7515
  23. 23.O.GLATTER, O.KRATKY, “Small Angle X-ray Scattering”, Academic Press, New York (1982), P.3~43