單層硫硒化鎢混合結構之合成與分析

本篇文章的主要工作內容是在於利用化學氣相沉積法(CVD)合成WS2以及WSe2，CVD的製程相當複雜，變數相當多且都會互相影響，本研究藉由改變實驗參數，觀察不同參數對結晶的影響，試著釐清並深入討論提出結晶的成長機制，包括還原氣氛(氫氣)、氣流型態、反應物的添加量以及反應物的位置等，進一步最佳化實驗參數去合成獨立或大面積的單層結晶，並將單層結晶做成元件量測材料的電學性質以及光電性質，最後以合成純相材料WS2、WSe2時所歸納的成長機制，實現WS2-WSe2混相結構的合成，希望能結合此二種材料優異的特性進一步去開發出能廣泛應用的半導體元件，透過參數調整，我們得到不同混合比例的混相結構，發現不同混合比例會使材料的光致螢光放光波長改變，也代表材料的能隙會因混合比例不同而改變。

關鍵字

二維材料

並列摘要

In this research, we used chemical vapor deposition to synthesize monolayer WS2、WSe2.The impact of growth parameters of WS2 and WSe2 was investigated , such as gas flow rate , reducing atmosphere(H2), amount of precursor .The high quality of monolayer WS2 and WSe2 was confirmed by optical microscopy ,atomic force microscopy(AFM) , photoluminescence (PL) and Raman spectroscopy. The growth mechanism was discussed and proposed. In addition, we report on electronics and optoelectrons properties based on back-gated field-effect transistors. The device of WS2 exhibited a excellent photoresponsivity of 63.8A/W. On the other hand, device of WSe2 is ambipolar , could be turned into either n-type or p-type electrical behavior. Finally, we show that hybrid WS2-WSe2 can be synthesized by chemical vapor deposition. PL of hybrid could be tunable by controlling the amount of precursors.

並列關鍵字

2D materials

參考文獻

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3. Zhu, B., et al., Anomalously robust valley polarization and valley coherence in bilayer WS2. Proceedings of the National Academy of Sciences, 2014. 111(32): p. 11606-11611.

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單層硫硒化鎢混合結構之合成與分析

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