Title

製備多熱點聚醯胺酸/氧化鋅/奈米銀核殼顆粒探討表面拉曼散射

Translated Titles

Preparation Multi-Hotspot of Poly(Amic Acid)/ZnO/Nano Silver Core-Shell Particles and Investigation Surface-Enhanced Raman Scattering

Authors

謝政諺

Key Words

核殼顆粒 ; 氧化鋅 ; 奈米銀 ; 表面增強拉曼散射 ; Core-shell particles ; Zinc oxide ; nano silver ; Surface Enhanced Raman scattering

PublicationName

中原大學化學工程研究所學位論文

Volume or Term/Year and Month of Publication

2016年

Academic Degree Category

碩士

Advisor

許克瀛

Content Language

繁體中文

Chinese Abstract

本研究製備聚醯胺酸/氧化鋅/奈米銀複合顆粒作為表面增強拉曼基材使用,利用先前實驗室製備出聚醯胺酸/氧化鋅複合顆粒當作粒種再添加奈米銀對氧化鋅殼層進行改質,進而製備出聚醯胺酸/氧化鋅/奈米銀複合顆粒,並利用SEM、TEM、XRD、EDX進行材料結構分析與利用UV-Visible進行光學性質分析。 聚醯胺酸/氧化鋅/奈米銀複合顆粒應用於表面增強拉曼散射,以此複合顆粒當作基材,將不同體積濃度的Rhodamine 6G(Rh 6G)染料滴在核殼顆粒上,得知染料(Rhodamine 6G)的濃度已減低至10-6也能展現一定的訊號強度,並可在低能量下作為光觸媒降解Rhodamine 6G,因此此複合顆粒可作為拉曼散射基材,同時增加了回收功能。

English Abstract

The aim of the work is to prepare Poly(amic acid)/Zinc Oxide/Nano silver core-shell particles,using as a Surface-Enchanced Raman Scattering .In the previous work,surface modification of ZnO shell of Poly(amic acid)/Zinc Oxide core shell spheres Ag nanoparticles was carried out.Thus,Ag nanoparticles will locate selectively at suitable sites on the surface of ZnO.Finally, poly(amic acid) / Znic Oxide/nano silver core-shell particles can be prepared and were characterized by SEM,TEM,XRD,EDX and used UV-Visible opticle properties analysis. Use the Polyamide acid/Zinc Oxide/Nano silver composite particles in surface can enhance the Raman scattering, as composite particles as our substrate , try different volume concentrations of Rhodamine 6G (Rh 6G) dye dripping on the core-shell particles can find the concentration of dye (Rhodamine 6G) has been reduced to 10-6 and have a certain degree of signal strength, also use the low energy in application of photocatalyst for Rhodamine 6G , base on this result, use these composite particles for Raman scattering substrate can increase the recycling for using.

Topic Category 工學院 > 化學工程研究所
工程學 > 化學工業
Reference
  1. 1.M. Agrawal, S. Gupta, M. Stamm, Recent developments in fabrication and applicationsof colloid based composite particles, J. Mater. Chem. 21 (2011) 615-627.
    連結:
  2. 2.W.Niea, P. Chen, Appl Surf Sci. 329 (2015) 158–164.
    連結:
  3. “Synthesis of porous small-sized ZnO nanoparticles and their gas-sensing performance”, Materials Letters157(2015)151–154.
    連結:
  4. Nur Hanis Hayati Hairom, Abdelbaki Benamor, “Synthesis of
    連結:
  5. minimal-size ZnO nanoparticles through sol–gel method:Taguchi
    連結:
  6. J.-S.Ahn , Ramchandra B. Pode , “Low temperature dielectric studies
    連結:
  7. of zinc oxide (ZnO) nanoparticles prepared by precipitation method”
    連結:
  8. Advanced Powder Technology 24 (2013) 331–335.
    連結:
  9. nanosheets for enhanced photocatalytic activity” Journal of Colloid and Interface Science 462 (2016) 9–18.
    連結:
  10. 12.Truong Thi Hanh,Ngyen Thui Thu, Nguyen Quoc Hien, Pham Ngoc An , Truong Thi Kieu Loan,Phan Thi Hoa“Preparation of silver nanoparticles fabrics against multidrug-resistant bacteria” Radiation Physics and Chemistry121(2016)87–92.
    連結:
  11. 14.A. Hebeish, Th. I. Shaheen, Mehrez E. El-Naggar, “Solid state synthesis of starch-capped silver nanoparticles”International Journal of Biological Macromolecules 87 (2016) 70–76.
    連結:
  12. 15.Lihui Wang, Jingming Zhong, Guolong Li, Jian-feng Chen, “Preparation of silver nanopowders by a controlled wet-chemical synthesis” Materials Letters.
    連結:
  13. 16.H. Vidya , B.E. Kumara Swamy, Mark Schell, “One step facile synthesis of silver nanoparticles for the simultaneous electrochemical determination of dopamine and ascorbic acid” Journal of Molecular Liquids 214 (2016) 298–305.
    連結:
  14. 17.Chengyin Li, Hui Liu, Penglei Cui, Feng Ye, Jun Yang,“Insight into the formation of hollow silver nanoparticles using a facilehydrothermal strategy” Particuology 24 (2016) 197–202.
    連結:
  15. 18.Lijuan Sun , Jiang He , Songsong An , Junwei Zhang , Dong Ren, “Facile one-step synthesis of Ag@Fe3O4 core–shell nanospheres for
    連結:
  16. 19.Sarita Kango, Susheel Kalia, Annamaria Celli , James Njuguna,
    連結:
  17. Youssef Habibi, Rajesh Kumar, “Surface modification of inorganic nanoparticles for development of organic–inorganic
    連結:
  18. 20.Ping Li , Lun Cai , Gang Wang , Da Chen Zhou , Jin Xiang , Yu Jun Zhang , Bao Fu Ding , Kamal Alameh , Qun Liang Song , “PEIE capped ZnO as cathode buffer layer with enhanced charge transfer ability for high efficiency polymer solar cells” Synthetic Metals 203 (2015) 243–248.
    連結:
  19. 22.Lan Wang, Lin Yong Song, Zhi Yin Chao, PengPeng Chen, Wang Yan Nie,Yi Feng Zhou, “Role of surface functionality on the formation of raspberry-likepolymer/silica composite particles: Weak acid–base interaction andsteric effect”Applied Surface Science 342 (2015) 92–100.
    連結:
  20. 23.Zhiyin Chao, Lan Wang, Linyong Song, Yifeng Zhoua,Wangyan Nie, Pengpeng Chen“Facile method to prepare poly(S-co-HEA)/Ag nanocomposite particleswith high efficient catalytic activity and surface enhanced Ramanscattering” Applied Surface Science 329 (2015) 158–164.
    連結:
  21. 24.Boris N.Khlebtsov , ZhonghuiLiu , JianYe , NikolaiG.Khlebtsov , “Au@Ag core/shell cuboids and dumbbells: Optical properties and SERS response” Journal of uantitative pectroscopy&adiative ransfer
    連結:
  22. 167(2015) 64-75.
    連結:
  23. 25.Chien WC, Yu YY, Chen PK,Thin Solid Films .519(2011)5274-9.
    連結:
  24. 26.Y.S. Tamgadge , A.L. Sunatkari , S.S. Talwatkar , V.G. Pahurkar , G.G. Muley , “Passive optical limiting studies of nanostructured Cu doped ZnO–PVA composite thin films ” Optical Materials 51 (2016) 175–184.
    連結:
  25. 27.R. Bhunia , A.K. Yadav , S.N. Jha , D. Bhattacharyya , S. Hussain , R. Bhar , A.K. Pal , “Probing local environment of Mn-doped nanocrystalline-ZnO/PVDF composite thin films by XPS and EXAFS studies” Polymer 78 (2015) 1–12.
    連結:
  26. 28.Juan Xie , Zhao Zhou , Yiwei Lian , Yongjing Hao , Pan Li , Yu Wei,, “Synthesis of α-Fe2O3/ZnO composites for photocatalytic degradation of pentachlorophenol under UV–vis light irradiation” Ceramics International 41 (2015) 2622–2625.
    連結:
  27. 29.Noriya Izu, Kazuhiko Shimada, Takafumi Akamatsu, Toshio Itoh, Woosuck Shin, Kentaro Shiraishi, Taketoshi Usui, “Polyol synthesis of Al-dopedZnO spherical nanoparticles and their UV–vis–NIR absorption properties” Ceramics International40(2014)8775–8781.
    連結:
  28. 30.Wanghui Chen, Chika Takai, Hadi Razavi Khosroshahi, Masayoshi Fuji, Takashi Shirai, “SiO2/TiO2 double-shell hollow particles: Fabrication and UV–Vis spectrum characterization” Advanced Powder Technology (2015).
    連結:
  29. 31.Sze-Mun Lam, Jin-Chung Sin, Ahmad Zuhairi Abdullah, Abdul Rahman Mohamed, “Transition metal oxide loaded ZnO nanorods: Preparation,characterization and their UV–vis photocatalytic activities” Separation and Purification Technology 132 (2014) 378–387.
    連結:
  30. 32.Cheng Chen,Xi Zhou,Taotao Ding,Jun Zhang,Shuai Wang,Juan Xu,Jingwen Chen, Jiangnan Dai , Changqing Chen, “Preparation and characterization of ZnO/SiO2/Ag nanoparticlesas highly sensitive substrates for surface-enhanced Ramans cattering” Materials Letters 165(2016)55–58.
    連結:
  31. nanoaggregates/SiO2 yolk–shell nanoprobes for surface-enhanced Raman scattering” Journal of Industrial and Engineering Chemistry 32 (2015) 34–38.
    連結:
  32. 34.Zhenjiang Li ,Kaixing Zhu, Qian Zhao, Alan Meng , “The enhanced SERS effect of Ag/ZnO nanoparticles through surface hydrophobic modification”Applied surface science.
    連結:
  33. 35.Yongjun Zhang , Cong Wang, Jinpeng Wang, Lei Chen, Jia Li , Yang Liu , Xiaoyu Zhao,Yaxin Wang, Jinghai Yang , “Nanocap array of Au:Ag composite for surface-enhanced Raman scattering” Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 152 (2016) 461–467.
    連結:
  34. 36.C. Zhang, B.Y. Man, S.Z. Jiang, C. Yang, M. Liua, C.S. Chen, S.C. Xu, H.W. Qiu,Z. Li,“SERS detection of low-concentration adenosine by silvernanoparticles on silicon nanoporous pyramid arrays structure” Applied Surface Science 347 (2015) 668–67.
    連結:
  35. 3.D. Nguyen, S. Ravaine, E. Bourgeat-Lami, E. Duguet, J. Mater. Chem. 20 (2010) 9392-9400.
  36. 4.M. D’Acunzi, L. Mammen, M. Singh, X. Deng, M. Roth, G.K. Auernhammer, H-J.Butt, D. Vollmer, Faraday Discuss. 146 (2010) 35-48.
  37. 5.Z. Qian, Z.C. Zhang, L.Y. Song, H.R. Liu, J. Mater. Chem. 19 (2009) 1297-1304.
  38. 6.S.J. Guo, S.J. Dong, E. Wang, J. Phys. Chem. C .113 (2009)5485-5492.
  39. 7.X. Wang, T. Akagi, M. Akashi, M. Baba, Mini-Rev, Org. Chem. 4 (2007)51-59.
  40. 8.Y.Z.Mao,S.Y.Ma n,W.Q.Li,J.Luo,L.Cheng,D.J.Gengzang,X.L.Xu.,
  41. 9.Ying Tao Chung , Muneer M. Ba-Abbad , AbdulWahab Mohammad,
  42. design optimisation” Materials and Design 87 (2015) 780–787.
  43. 10.Amrut S. Lanje , Satish J. Sharma , Raghumani S. Ningthoujam ,
  44. 11.Yu Miao , Haijiao Zhang , Shuai Yuan , Zheng Jiao , Xuedong Zhu ,
  45. “Preparation of flower-like ZnO architectures assembled with
  46. 13.Subhadip Das, Dinabandhu Sasmal, Sagar Pal, Haradhan Kolya, Akhil Pandey,Tridib Tripathy, “Starch based biodegradable graft copolymer for the preparationof silver nanoparticles” International Journal of Biological Macromolecules 81 (2015) 83–90 Contents lists.
  47. reproducible SERS substrates” Journal of Molecular Structure 1046 (2013) 74–81.
  48. nanocomposites—A review” Progress in Polymer Science 38 (2013) 1232– 1261.
  49. 21.Jiaxin Lian , Yosra Agban , Soshan Cheong , Rhiannon P. Kuchel , Allan Raudsepp ,Martin A.K. Williams , Ilva D. Rupenthal, Anna Henning , Richard D.Tilley ,Geoff Holmes , Sujay Prabakar, “ZnO/PVP nanoparticles induce gelation in type I collagen” European Polymer Journal 75 (2016) 399–405.
  50. 33.Taegyu Kang , Sinyoung Jeong , Homan Kang , Jaehi Kim, Hyung-Mo Kim , San Kyeong , Sang Hun Lee , Dae Hong Jeong , Bong-Hyun Jun , Yoon-Sik Lee , “Fabrication of Ag
  51. 37.吳俊逸,碩士論文,中原大學化工所,2007。
  52. 38.吳俊逸,博士論文,中原大學化工所,2015。