Title

含雙醯胺吡啶與V字型配位基之二價鈷、鎳配位高分子的合成、結構與性質研究

Translated Titles

Synthesis, Structures and Properties of Cobalt(II) and Nickel(II) Coordination Polymers Containing Dipyridyl Amide and V-shaped Dicarboxylate Ligands

Authors

吳宗泰

Key Words

配位高分子 ; 雙醯胺吡啶 ; V字型配位基 ; coordination polymers ; Dipyridyl amide ; v-shaped

PublicationName

中原大學化學研究所學位論文

Volume or Term/Year and Month of Publication

2014年

Academic Degree Category

碩士

Advisor

陳志德

Content Language

繁體中文

Chinese Abstract

一系列含 N,N’-二-(4-吡啶)辛二醯二胺 (L)與V字型配位基的鈷鎳錯合物已藉由水熱反應合成: {[Co(L)(MBA)]2H2O}n (H2MBA = diphenylmethane-4,4’-dicarboxylic acid), 1, {[Ni(L)(MBA)]2H2O}n, 2, {[Co2(L)(MBA)2]2CH3OH}n, 3 , {[Co2(L)(MBA)2]}n , 4 ,{[Co2(L)(OBA)2]7CH3OH}n [H2OBA = 4,4’-oxybis(benzoic acid)], 5, {[Co(L)(H2hfipbb)]2H2O}n [H2hfipbb=4,4′-(hexafluoroisopropylidene)bis(benzoic acid)], 6, {[Co(L)(SDA)].H2O}n (H2SDA = 4,4’-sulfonyldibenzoic acid), 7, {[Co2(L)(MBA)2]2CH3OH}n , 3, {[Ni(L)(SDA)]2H2O}n, 8。 這些化合物藉由單晶X-ray繞射儀來鑑定其結構,更進一步利用元素分析儀、粉末X-ray繞射儀、熱種分析儀來研究化合物的特性。其中化合物5 對於二氧化碳的吸附較氫氣及氮氣來的出色。 化合物1和2是利用一維的螺旋鏈形成1D→2D多具連鎖的結構。化合物3為一個2-fold 交互貫穿的結構,每個單元具有(42688104)(4)2-2,6L1的拓樸學。化合物4為一個2D→3D多聚連鎖的結構,每個單元具有(42688104)(4)2-2,6L1的拓樸學。化合物5為一個3-fold交互貫穿的結構,每個單元具有(63)(698)-gra的拓樸學。化合物6到8為2 或 3 fold 交互貫穿的結構,每個單元都具有(64810)(6)的拓樸學。而每個交互貫穿的結構可以進一步和相鄰兩層鏈在一起形成少見的2D→3D多聚連鎖的結構。

English Abstract

A series of Co(II) and Ni(II) coordination polymers containing N,N-di(4-pyridyl)suberoamide (L) and V-shaped dicarboxylate ligands: {[Co(L)(MBA)]2H2O}n (L = N,N’-di(4-pyridyl)suberoamide; H2MBA = diphenylmethane-4,4’–dicarboxylic acid), 1, {[Ni(L)(MBA)]2H2O}n, 2, {[Co2(L)(MBA)2]2CH3OH}n , 3, {[Co2(L)(MBA)2]}n, 4, {[Co2(L)(OBA)2]7CH3OH}n [H2OBA = 4,4’–oxybis(benzoic acid)], 5, {[Co(L)(H2hfipbb)]2H2O}n [H2hfipbb = 4,4′-(hexafluoroisopropylidene)bis(benzoic acid)], 6, {[Co(L)(SDA)]H2O}n (H2SDA = 4,4’-sulfonyldibenzoic acid), 7, {[Ni(L)(SDA)]2H2O}n, 8, are reported, which were prepared by hydrothermal reactions. Their structures were determined by single crystal X-ray diffraction analyses and further characterized by elemental analyses, powder X-ray diffraction and thermal gravimetric analysis. The CO2 capture is preferable to N2 and H2 in the gas sorption for the desolvated product of 5. Complex 1 and 2 are 1D → 2D polycatenanes derived from the helical channels. Complex 3 shows the (42688104)(4)2-2,6L1 topology with a 2-fold interpenetrating mode. Complex 4 shows 2D layers with the (42688104)(4)2 2,6L1 topology, which catenate to each other to form a 2D → 3D inclined polycatenation framework. Complex 5 shows (63)(698)-gra topology with a 3-fold interpenetrating mode. The unusual topological features of 6 - 8 consists of the 2- and 3-fold interpenetrated layers with the (64810)(6) topology, which are further catenated to the two adjacent such sheets in parallel fashion to give overall unique 2D → 3D polycatenated frameworks.

Topic Category 基礎與應用科學 > 化學
理學院 > 化學研究所
Reference
  1. [4] S. R. Batten and R. Robson, Angew. Chem. Int. Ed., 1998, 37, 1460-1494.
    連結:
  2. [5] S. R. Batten, S. M. Neville and D. R. Turner, Coordination Polymers: Design, Analysis and Application, 2009, 67-77.
    連結:
  3. [6] L. Carlucci, G. Ciani and D. M. Proserpio, Coord. Chem. Rev., 2003, 247.
    連結:
  4. [7] S. Su, C. Qin, Z. Guo, H. Guo, S. Song, R. Deng, F. Cao, S. Wang, G. Li and H. Zhang. CrystEngComm, 2011, 13, 2935-2941.
    連結:
  5. [9] (a) J.-J. Cheng, Y.-T. Chang, C.-J. Wu, Y.-F. Hsu, C.-H. Lin, D. N.Proserpio and J. D. Chen. CrystEngComm, 2012, 14, 537. (b) P. C. Cheng, C. W. Yeh, Wayne Hsu, T. R. Chen, H. W. Wang, J. D. Chen and J.-C. Wang. Cryst. Growth Des., 2012, 12, 943-953. (c) M.-J. Sie, Y.-J. Chang, P. T. Kuo, C.-W. Yeh, C.-F. Cheng, J.-D. Chen and J.-C. Wang. CrystEngComm, 2012, 14, 5505. (d) P. -C. Cheng, M. -H. Wu, M. -Y. Xie, W. -J. Huang, H. -Y. He, T. -T. Wu, Y. -C. Lo, D. M. Proserpio and J. -D. Chen. CrystEngComm, 2013, 15, 10346-10357.
    連結:
  6. [10] S. Kitagawa, R. Kitaura and S. Noro. Angew. Chem. Int. Ed., 2004, 43, 2334 –2375.
    連結:
  7. [12] A. L. Spek, J. Appl. Crystallogr. 2003, 36, 7−13.
    連結:
  8. [13] S.-C. Chen, Z.-H. Zhang, K.-L. Huang, Q. Chen, M.-Y. He, A.-J. Cui, C. Li, Q. Liu and M. Du. Cryst. Growth Des., 2008, 8, 3437-3445. CrystEngComm, 2013, 15, 9533-9561.
    連結:
  9. 440-443. (b) Y.-L. Liu, K.-F. Yue, D.-S. Li, Y. Yu, L. Hou and Y.-Y. Wang. CrystEngComm, 2013, 15, 2791-2794. (c) Y. Bu, F. Jiang, K. Zhou, X. Li, L. Zhang, Y. Gai and M. Hong. CrystEngComm, 2013, 15, 8426-8429. (d) X.-Q. Yao, J.-S. Hu, M-D. Zhang, L. Q, Y.-Z. Li, Z.-J. Guo and H.-G. Zheng. Cryst. Growth Des., 2013, 13, 3381-3388. (e) L. Carlucci, G. Ciani, S. Maggini and D. M. Proserpio. Cryst. Growth Des., 2008, 8, 162-165. (f) L. Qin, J.-S. Hu, Y.-Z. Li and H.G Zheng. Growth Des., 2012, 12, 403-413. (g) X-Q. Yao, D.-P. Cao, J.-S. Hu, Y.-Z. Li, Z.-J. Guo and H.-G. Zheng. Growth Des., 2011, 11, 231-239. (h) X-T. Zhang, D. Sun, B. Li, L.-M. Fan, B. Li and P.-H. Wei. Growth Des., 2012, 12, 3845-3848. (i) M-D. Zhang, L. Qin, H.-T. Yang, Y.-Z. Li, Z.-J. Guo and H.-G. Zheng. Growth Des., 2013, 13, 1961-1969.
    連結:
  10. [1] C. N. Morrison, A. K. Powell and G. E. Kostakis, Cryst. Growth Des., 2011, 11, 3653-3662.
  11. [2] Y. Hao, B. Wu, S. Li, B. Liu, C. Jia, X. Huang and X. Yang. CrystEngComm., 2011, 13, 6285-6292.
  12. [3] Y.-H. Liao, Wayne Hsu, C.-C. Yang, C.-Y. Wu, J.-D. Chen and J.-C. Wang. CrystEngComm, 2013, 15, 3974.
  13. [8] L. Liu, C. Huang, Z. Wang, D. Wu, H. Hou and Y. Fan. CrystEngComm, 2013, 15, 7095-7105.
  14. [11] (a) H. Wu, J. Yang, Y.-Y. Liu and J-F. Ma. Cryst. Growth Des., 2012, 12, 2272-2276. (b) X. Xu, X. Zhang, X. Liu, L. Wang and E. Wang. CrystEngComm, 2012, 14, 3264-3270. (c) S. Wang, D. Li, J. Dou and D. Wang, Acta Cryst. 2010, C66, m118–m121. (d) Q.-Y. Yang, S.-R. Zheng, R. Yang, M. Pan, R. Cao and C.-Y. Su. CrystEngComm, 2009, 11, 680-685. (e) H. Guo, D. Qiu, X. Guo, S. R. Batten and H. Zhang. CrystEngComm, 2009, 11, 2611-2614. (f) S. Banfi, L. Carlucci, E. Caruso, G. Ciani and D. M. Proserpio. Cryst. Growth Des., 2004, 4, 29-32. (g) F. -L. Hu, Y. -Q. Gu, L. -G. Zhu, S. -L. Yang, H. Wei and J. -P. Lang. CrystEngComm, 2013, 15, 9553-9561.
  15. [14] (a) B. Xu, Z. Lin, L. Han and R. Cao. CrystEngComm, 2011, 13,
  16. [15] (a) Y. -F. Hsu, H. -L. Hu, C. -J. Wu, C. -W. Yeh, D. M. Proserpio and J.-D. Chen. CrystEngComm, 2009, 11, 168-176. (b) 中原大學化學系朱陳郁涵碩士論文2011年
  17. [16] D. S. Raja, J. -H. Luo, C. -Y. Wu, Y. -J. Cheng, C. -T. Yeh, Y. -T. Chen, S. -H. Lo, Y. -L. Lai and C. -H. Lin. Growth Des., 2013, 13, 3785-3793.
  18. [17] D. -H. Hong and M. P. Suh. Chem. Commun., 2012, 48, 9168-9170.