Title

含銻、鉍之鐵羰基化合物和鉛之鉻羰基化合物其合成、結構與反應性研究

Authors

陳榮倉

Key Words

羰基化合物 ; carbonyl cluster

PublicationName

臺灣師範大學化學系學位論文

Volume or Term/Year and Month of Publication

2000年

Academic Degree Category

碩士

Advisor

謝明惠

Content Language

繁體中文

Chinese Abstract

[Et4N]3[Bi{Fe(CO)4}4] 與 n-BuBr在CH3CN中加熱41∼42 ℃反應24小時後,再加入HOAc處理,可得到兩個中性的產物,一為雙聚合物 [n-BuBiFe(CO)4]2 (dimer),另一為高分子聚合物 [n-BuBiFe(CO)4]¥ (polymer)。此外,若將 [Et4N]3[Bi{Fe(CO)4}4] 與HCoCCH2Br的反應,則會形成一個離子性的產物[Et4N]2[BrBiCH2C(CO)CH(CO)Fe(CO)3]2,若進一步將 [Et4N]3[Bi{Fe(CO)4}4] 與CBr4反應,其產物是一個Bi雙核的錯化合物 [Et4N]2[Bi2Br6Fe(CO)4]。然而若是在反應當中加入過量的HCoCCH2Br或是H2C=CHCH2Br,則會產生一系列的氧化性產物Bi2Fe3(CO)9、 [Et4N][BiFe3(CO)10] 、[Et4N]2[Bi4Fe4(CO)13]和 [Et4N]2[Bi4Fe5(CO)17]

English Abstract

The reaction of [Et4N]3[Bi{Fe(CO)4}4] with n-BuBr followed by HOAc gives two neutral compounds. One is the dimer complex [n-BuBiFe(CO)4]2, and the other is the polymer complex [n-BuBiFe(CO)4]¥. Besides, [Et4N]3[Bi{Fe(CO)4}4] reacts with HCoCCH2Br to form the ionic complex [Et4N]2[BrBi(C(O)C3H3C(O))Fe(CO)3]2. Further treatment of [Et4N]3[Bi{Fe(CO)4}4] with CBr4 gives the dinuclear complex [Et4N]2[Bi2(Br)2(Fe(CO)4)Br4]. However, if [Et4N]3[Bi{Fe(CO)4}4] is treated with excess H2C=CHCH2Br or HCoCCH2Br, a series of oxidation products Bi2Fe3(CO)9, [Et4N][BiFe3(CO)10], [Et4N]2[Bi4Fe4(CO)13], and [Et4N]2[Bi4Fe5(CO)17] are obtained.

Topic Category 基礎與應用科學 > 化學
理學院 > 化學系
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