Title

合成新二苯并[a,c]二氮蒽之酸衍生物盤型液晶

Translated Titles

Synthesis of new Dibenzo[a,c]phenazine acid derivative discotic liquid crystal

Authors

吳侑任

Key Words

離子液晶 ; 液晶 ; 二苯并[a,c]蒽 ; 氫鍵 ; 醯胺 ; 盤狀分子 ; ionic liquid crystal ; dibenzo[a,c]phenazine ; discotic ; liquid crystal ; amide ; hydrogen bonding

PublicationName

中山大學化學系研究所學位論文

Volume or Term/Year and Month of Publication

2014年

Academic Degree Category

碩士

Advisor

王志偉

Content Language

繁體中文

Chinese Abstract

本論文主旨是設計以二苯并[a, c]二氮蒽為中心結構經由將酸基的置換形成醯胺進而使得盤型分子具備氫鍵作用力。藉由偏光顯微鏡、微差掃描熱卡計以及X光粉末繞射儀對該系列分子進行鑑定,並探討氫鍵作用力的有無對盤形液晶分子排列上的差異。 此外也設計以二苯并[a, c]二氮蒽酸與胺類形成離子液晶,探討離子鍵是否會對盤型液晶分子造成排列堆疊上的影響。

English Abstract

We have synthesized the derivative of dibenzo[a,c]phenazine acid as a exchange form acid to amide. In order to discuss the difference between the presence of the hydrogen bonding interaction, POM, DSC, and XRD are used to confirm the self-assembly packing of the derivatives. In addition, we make use of dibenzo[a,c]phenazine acid and some certain kinds of amine to form ionic liquid cyrstal, and the properties of ionic bonds that influence self-assemble packing are also mentioned in this thesis as well.

Topic Category 基礎與應用科學 > 化學
理學院 > 化學系研究所
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Times Cited
  1. 葉凱翔(2015)。因素控制苯-1,3,5-三醯胺液晶之超分子組裝。中山大學化學系研究所學位論文。2015。1-103。