酞花青染料之於染料敏化太陽能電池的應用與探討

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酞花青染料之於染料敏化太陽能電池的應用與探討

Study and Application of Phthalocyanato Ruthenium Dye for Dye-Sensitized Solar Cells

陳庭萱 , Masters　　Advisor：林俊彬　　Co-advisor ：陳兆勛

繁體中文

染料敏化太陽能電池；共敏化；染料混摻；釕錯合物； dye-sensitized solar cell ； co-sensitized ； blending dye ； phthalcyano ruthenium complex

Abstract │ Reference (60) │ Altmetrics

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The main purpose of this research is to study co-sensitization in the dye-sensitized solar cell (DSSC) .
For DSSC, photon-to-electron conversion efficiency is depending on the dye absorption spectrum and the shifting rate of electron from dye to electrode. The absorption UV-vis spectrum of dyes in DSSC is generally in 400nm-600nm region ,but  it is weak beyond 600nm.Therefore ,in this study we blend dyes in order to extend the range of light absorption and improve the efficiency of DSSC further.
The common phthalcyano ruthenium complex, bis(4-carboxypyridine)
-(phthalocyanainato) ruthenium(II) in near IR region are chosen to fabricate co-sensitized DSSC .ruthenuim complex, N719 (cis-di(thiocyanato)-bis(2,2'-bipyridyl -4,4'-dicarboxylic acid)-ruthenium(II)) in blue light region, and We want to extend light absorption and improve efficientcy by this process.    
The results reveal that the energy band of N719 and bis(4-carboxypyridine)
-(phthalocyanainato) ruthenium(II) can macth well.So the efficiency of DSSCs is enhancing near 10％.

Reference ( 60 ) 〈TOP〉

(1) Gratzel, Michael, Photoelectrochemical cells. Nature 414 (6861), 338 (2001).
連結：
(3) Markvart, T., Solar Electricity, 2nd ed. (John Wiley & Sons, 2000).
連結：
(7) A. J. Bard, “Photoelectrochemistry,” Science, 207, 139-144 (1980).
連結：
(8) N. S. Lewis, “Artificial photosynthesis,” Am. Sci., 83, 534-541 (1995).
連結：
(11) D. M. Chapin, C. S. Fuller, G. L. Pearson, A new silicon p-n junction photocell for converting solar radiation into electrical power. Journal of Applied Physics 25, 676 (1954).
連結：

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