聚苯胺奈米纖維與銀金屬複合材料之製備

王宛婷

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聚苯胺奈米纖維與銀金屬複合材料之製備

The fabrication of PANI nanofibers/Ag composite

王宛婷 , Masters　　Advisor：廖文彬　　

繁體中文

聚苯胺；網狀纖維；型態；二次成長；複合材料； polyaniline ； network nanofibers ； morphology ； secondary growth ； composite

Abstract │ Reference (80) │ Altmetrics

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This research focused on how to take advantage of certain conditions to control the morphology of polyaniline , we use three ways: first, adjusting the ratio between the APS /Aniline, control the amount of sulfate radical, so that the polyaniline appear the morphological changes of the trend; by adding silver nitrate to the polymerization, polyaniline will generate the morphological changes; at different polymerization time polyaniline appears different forms and morphologies.

We use two different morphologies of polyaniline to reduce the silver metal by the differences between the conductivity and chemical structure, which will result in different amount and morphologies of silver metal.

Finally, we utilize one-pot synthesis reactions by one-time mixing of silver nitrate, aniline and APS to fabricate the PANI nanofibers/Ag composite. In addition to causing changes in the polyaniline morphologies, we believe that the reduction reaction of silver may be related to the polymerization at the same time.

Reference ( 80 ) 〈TOP〉

[1] H. Shirakawa, E. J. Louis, A. G. MacDiarmid, C. K. Chiang, A. J. Heeger, J.
Chem.Soc. Chem. Commun. 16, 578 (1977).
[2] H. Shirakawa, Angew. Chem. Int. Ed., 40, 2574 (2001).
[3] A. G. MacDiarmid, Angew. Chem. Int. Ed., 40, 2581 (2001).
[4] A. J. Heeger, Angew. Chem. Int. Ed., 40, 2591 (2001).

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