橢球在充滿無鹽電解質溶液之球型孔洞內之電泳

謝明叡

doi:10.6342/NTU.2009.02589

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橢球在充滿無鹽電解質溶液之球型孔洞內之電泳

Electrophoresis of a Spheroid in a Spherical Cavity Filled with a Salt-Free Solution

謝明叡 , Masters　　Advisor：徐治平　　

英文 DOI： 10.6342/NTU.2009.02589

電泳；固定表面電荷密度；橢球粒子在球型孔洞中；無鹽電解質溶液；泳動度；牛頓流體；邊界效應； electrophoresis ； constant surface charge density ； spheroid in spherical cavity ； salt-free solution ； mobility ； boundary effect

Abstract │ Reference (37) │ Altmetrics

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The electrophoretic behavior of a spheroid at an arbitrary position in a spherical cavity is analyzed numerically under a salt-free condition, that is, the liquid phase contains only counterions which come from the dissociation of the functional groups of particle. The influences of the key parameters of the system under consideration, including the total amount of surface charge on the particle, the valence of the counterion, the relative size of the cavity, the aspect ratio of the particle and its position in the cavity. Several interesting results were observed. For example, if the total amount of surface charge is fixed, the magnitude of the electrophoretic mobility for various types of particle generally ranks as prolate>sphere>oblate. The effect of counterion condensation yields a small value of electrophoretic mobility in the case of high valence of the counterions. In addition, it exhibits a local maximum in the electrophoretic mobility as the aspect ratio of the particle varies.

Reference ( 37 ) 〈TOP〉

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連結：
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