中空纖維液相微萃取法結合氣相層析質譜儀偵測塑膠容器溶出之抗氧化劑

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中空纖維液相微萃取法結合氣相層析質譜儀偵測塑膠容器溶出之抗氧化劑

Determination of antioxidants leached from plastic containers by hollow fiber liquid-phase microextraction and gas chromatography-mass spectrometry

林姿瑩 , Masters　　Advisor：鄭政峯　　

繁體中文

中空纖維液相微萃取法；抗氧化劑；塑膠包裝溶出；氣相層析質譜儀； Antioxidants ； Hollow fiber liquid-phase microextraction ； Plastic containers ； GC-MS

Abstract │ Reference (83) │ Altmetrics

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Plastics are the most commonly using materials for the food packaging. All polymeric materials are oxygenated during processing and usage. Therefore, it is necessary to add antioxidants to all polyalkenes in order to slow down their degradation and oxidation. These polymeric additives may leach from plastic containers into foods and beverages during the processing or storage.
  In this study, we developed an analytical method to determine the trace amount of antioxidants leaching from plastic packaging into water by hollow fiber liquid-phase microextraction (HF-LPME) coupled with gas chromatography-mass spectrometry (GC-MS). Three synthetic antioxidants, butylhydroxyanisole (BHA), butylhydroxytoluene (BHT), and bisphenol A (BPA) were successfully extracted from aqueous samples using HF-LPME procedure. The HF-LPME extraction parameters such as the extraction solvent, stirring rate, extraction time, hollow fiber length and salt concentration were optimized using spiked water samples. The linear range for BHA, BHT were 0.5~50 ng/mL, and BPA was 0.1~100 ng/mL. The detection limits were 0.07 ng/mL for BHA, 0.3 ng/mL for BHT, and 0.1 ng/mL for BPA. The results of this study reveal the adequacy of HF-LPME/GC-MS method for analyzing the antioxidants leached from plastic containers. The concentrations of BHT leached from plastic containers into water were 0.51 ng/mL and 0.57 ng/mL for polycarbonate (PC) and polystyrene (PS), respectively. This new simple method is affordable, efficient and convenient for extraction and determination of very low concentration of antioxidants in aqueous samples.

Reference ( 83 ) 〈TOP〉

2.Dopico-García, M. S.; López-Vilariño, J. M.; González-Rodríguez, M. V., Determination of antioxidant migration levels from low-density polyethylene films into food simulants. J. Chromatogr. A 2003, 1018, (1), 53-62.
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3.Yamamoto, T.; Yasuhara, A.; Shiraishi, H.; Nakasugi, O., Bisphenol A in hazardous waste landfill leachates. Chemosphere 2001, 42, (4), 415-418.
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5.Gächter, R.; Müller, H., Plastics additives handbook: stabilizers, plasticizers, fillers, reinforcements, colorants for thermoplastics. 4th ed.; Hanser/Gardner: 1993.
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8.Howard, P. H.; M.Meylan, W., Handbook of Physical Properties of Organic Chemicals. CRC: 1997.
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9.Branen, A., Toxicology and biochemistry of butylated hydroxyanisole and butylated hydroxytoluene. J. Am. Oil Chem. Soc. 1975, 52, (2), 59-63.
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