The purposes of this study were to investigate situation of students’ intelligence, learning environment satisfaction, learning attitude in electric/electronic cluster of vocational high school (EEVHS), to explore factors affecting those, and to construct path model that affect students’ learning attitude and academic achievement. To use obtained data including learning environmental satisfaction (component of school environment, home environment, teaching method and subject matter), learning attitude (component of learning interest, learning habit, learning anxiety, self-efficiency, practicability), intelligence (component of numeric reasoning, abstract reasoning, verbal reasoning), 90th academic achievement (component of Chinese, English, mathematics, electronics, basic electricity) that convert from raw score to standardized score. Then the statistical methods used in this study were t-test, one way analysis of variance, and path analysis. The conclusions of this study were as follows: 1. The verbal reasoning was lower than average, however, numeric reasoning and abstract reasoning were closer to average for student in EEVHS, Taipei. 2. In the aspect of affecting students’ learning attitude in EEVHS : (1)individual background : whether work after school, traffic time per day, the time to read per week. (2)learning environmental satisfaction. 3. In the aspect of affecting students’ academic achievement in EEVHS : (1)individual background : the time to read per week. (2)intelligence. (3)learning environmental satisfaction. (4)learning attitude. 4. The path model was demonstrated for affecting students’ learning attitude and academic achievement in EEVHS. In finally, according to insufficiency of sampling, variables, methodology in this study, and new ideal got from studying researcher provided the some suggestions to follow-up studies in the future.