利用BAA、PPI或TPGA製備含偶氮苯全像儲存材料之合成與特性分析

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利用BAA、PPI或TPGA製備含偶氮苯全像儲存材料之合成與特性分析

Synthesis and Characterization of Azobenzene with BAA、PPI、or TPGA for Holographic Storage

王祿宇 , Masters　　Advisor：蘇威宏　　

繁體中文

基材；甲基紅；偶氮苯；光儲存材料；離子鍵； Substrate ； Azobenzene ； Optical storage ； Ionic bonding ； Methyl Red

Abstract │ Reference (62) │ Altmetrics

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In this study, we prepared several azobenzene composites for optical storage. The light-induced interconversion allows azobenzene composites to be used as rewritable and erasable optical storage materials. Four different materials were selected as the incorporating materials, which were used to combine with the azobenzene material (2-{[4-(dimethylamino)phenyl]diazenyl} benzoic acid, Methyl Red, MR). They were ((3-Aminopropyl)triethoxysilane, APTES, AP), (Bis(3-aminopropyl)amine, BAA), (Polypropylenimine tetramine dendrimer, PPI) and ({Trimethylolpropane tris[poly(propylene glycol), amine terminated] ether}, TPGA). These azobenzene composites were formed by ionic bonding, which reduces the oppertunity of the phase separation and enhances the thermal stability for long term preservation. 
The diffraction efficiency of the composites MR/AP, MR/BAA, MR/PPI, MR/TPGA, were 19%, 17%, 16% and 18%. Atomic force microscopy revealed that surface variation of these composites was 768,758, 1467 and 729 nm, respectively, while N&amp;K results show that the sample thickness before holographic recording was 1422nm、1047nm、2148nm、762nm, respectively.

Reference ( 62 ) 〈TOP〉

[3] K. Curtis, W.L. Wilson, M. Tackitt, A.J. Hill, S. Campbell, Holographic data storage, Springer, 2000, pp. 359-368.
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[4] D. Staebler, W. Burke, W. Phillips, J. Amodei, Applied Physics Letters, 26 (1975) 182-184.
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[8] Y. P. Tseng, master thesis,National Sun Yat-sen University (2014).
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[10] D. Gabor, Nature, 161 (1948) 777-778.
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[13] S. Yoshida, K. Yamamoto, H. Kurata, M. Yamamoto, Progress In Electromagnetics Research Symposium Proceedings, Stockholm, Sweden, Aug. 687, (2013) 12-15.
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