Zn(S,O)和CZTSe的相互擴散現象研究及其在太陽電池之應用

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Zn(S,O)和CZTSe的相互擴散現象研究及其在太陽電池之應用

An interdiffusion study of a Zn(S,O)/CZTSe bilayer structure for photovoltaic applications

曾宗義 , Masters　　Advisor：曾百亨　　

繁體中文

濺鍍法；界面擴散； Zn(S,O) ； CZTSe ； sputtering ； interdiffusion ； Zn(S,O) ； CZTSe

Abstract │ Reference (38) │ Altmetrics

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This experiment tried to use multiple methods to make ZnS thin film and dope O to form ZnS1-xOx (Zn(S,O)) thin film, and finally selected Reactive Sputtering as the most fittable method. Form ZnS thin film formed by Reactive Sputtering with XRD and assure if the film was single phase or not. Next dope the oxygen with proportion PO2/Ptotal =1% to form ZnS1-xOx thin film and estimated the value of x was 0.2 approximately.
After Zn(S,O) thin film formed, replaced CdS to form on Cu2ZnSnSe4 (CZTSe). The result revealed the adhesion was not good observed from SEM figure and the interdiffusion was not obvious observed from GIXRD figure. To improve the scale of interdiffusion and adhesion, anneal the factor for two minutes on 400oC and 500oC separately. The result revealed the adhesion was better than before annealing on SEM gragh, the peak value of Zn(S,O) disappeared on 500oC, but the peak value of Zn(S,O) existed on 400oC. However, the scale of interdiffusion did not broaden apparently from GIXRD figure.

Reference ( 38 ) 〈TOP〉

[3] H. Zhou, Q. Chen, G. Li, S. Luo, T. B. Song, H. S. Duan, Z. Hong, J. You, Y. Liu, Y. Yang, “Interface engineering of highly efficient perovskite solar cells” , Science, 345, 542, 2014.
連結：
[4] Q. Guo, H. W. Hillhouse, R. Agrawal, “Synthesis of Cu2ZnSnS4 Nanocrystal Ink and Its Use for Solar Cells”, Journal of the American Chemical Society, 131, 11672, 2009.
連結：
[7] Y. M. Chang, H. W. Su, Y. Z. Zhu, G. D. Chen, “Band-gap bowing coefficients in large size-mismatched II-VI alloys: first-principles calculations”, Physical Review B, 74, 233202, 2006.
連結：
[8] C. Platzer-Björkman, T. Törndahl, D. Abou-Ras, J. Malmström, J. Kessler, L. Stolt, “Zn(O,S) buffer layers by atomic layer deposition in Cu(In,Ga)Se2 based thin film solar cells: Band alignment and sulfur gradient”, Journal of Applied Physics, 100, 44506, 2006.
連結：
[12] S. K. Pandey, S. Pandey, V. Parashar, R. S. Yadav, G. K. Mehrotraa, A. C. Pandey, “Bandgap engineering of colloidal zinc oxysulfide via lattice substitution with sulfur”, nanoscale, 6, 1062, 2014.
連結：

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