以電弧爐還原碴製成複合無機聚合物之研究

林湧昱

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以電弧爐還原碴製成複合無機聚合物之研究

Composite Geopolymer Produced by Using Electric-arc Furnace Reductive Slag

林湧昱 , Masters　　Advisor：黃偉慶　　

繁體中文

鹼活化技術；電弧爐還原碴；無機聚合物； electric-arc furnace reductive slag ； geopolymer ； alkali-activator

Abstract │ Reference (47) │ Times Cited (2) │ Altmetrics

Abstract 〈TOP〉

Parallel Abstract 〈TOP〉

Electric arc furnace reductive slag contains the characteristics of silicon, aluminum, calcium is a multi-type calcium aluminum silicate materials, Si4+, Al3+, Ca2+ in an alkaline solution can be isolated, and the mutual bond formation of Si-O-Si and CSH gel the coexistence composite geopolymer. In this paper, the electric-arc furnace reductive slag produced composite geopolymer mortar specimens for physical and chemical performance and micro explore analysis, and the use of slag to replace the amount of reductive slag to improve the insufficient strength and shrinkage Analysis and Discussion.
The results showed that the strength analysis found that the higher the fineness of grind of reductive slag, the compressive strength has the best range, and mortar specimens curing temperature to improve the compressive strength increases, and the performance of mortar mixing time, the compressive strength increased with the mixing time increase with, but the strength increase of the result is not significant. Slag to replace reductive slag in terms of compressive strength, the slag replaced by the increase in the compressive strength increase, but the setting time decreases.
Microscopic analysis of reductive slag produced composite geopolymer mortar specimens in 8%(by Na2O) of Ca2+ into the cut-off point; To the purely reductive slag in the drying shrinkage test, 8%(by Na2O) cut-off point, Drying shrinkage of more than 8%(by Na2O) percent less than 8%(by Na2O) below the CSH gel was reduced by Ca2+ with AlO4 reaction.; Slag to replace reductive slag, the drying shrinkage with the slag to replace the amount of increase is reduced.

Reference ( 47 ) 〈TOP〉

戴詩潔，「高嶺石鋁矽酸鹽聚合材料之研究」，碩士論文，台北科技大學材料及資源工程研究所(2005)。
連結：
郭硯華，「以鹼活化技術資源化電弧爐煉鋼還原碴之研究」，碩士論文，國立中央大學土木工程研究所(2007)。
連結：
張瑜文，「水庫淤泥應用於無機聚合膠結材」，碩士論文，國立成功大學土木研究所(2008)。
連結：
陳志賢，「含矽質廢棄物之無機聚合物」，博士論文，國立成功大學土木研究所(2009)。
連結：
Bakharev T., Sanjayan J. G., and Cheng, Y. B.(1999),“ Alkali activation of Australian slag cement,”Cement and Concrete Research, 29(1), pp. 113-120.
連結：

Times Cited (2) 〈TOP〉

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