- 期刊
理想氣體化學反應|ν_1|R_1 + |ν_2|R_2□|ν_p| P在恆溫恆壓下，反應達平衡時，反應式及反應物之符合條件的數學論證
Mathematical Verification of the Suitable Condition of Reactant and Reaction Equation in Chemical Equilibrium for the Chemical Reaction of Ideal Gases |ν_1|R_1+|ν_2|R_2 □ |ν_p|P Under Isothermal and Isobaric States
並列摘要
In this paper , we discuss that the result of mathematical exercises of first differentiating and second differentiating the mixing entropy of ideal gases with respect to extent of reaction at constant pressure and temperature. The minimum value of reaction free energy is ver ified indirectly in chemical equilbirium. On the basis of the relative formula of reaction mixing entropy Δ_rS_(mix)=0, it is derived to deduce and illustrate the fact that the suitable cond ition of reaction equation is |ν_2|＜|ν|≤|ν_1| and ν＜0, but only |ν_2|＜|ν| of reactant is established.
延伸閱讀
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