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含雙醯胺雙吡啶配位基之配位高分子:合成、結構、糾纏現象與結構轉換

Coordination Polymers Based on Bis-pyridyl-bisamide Ligands: Synthesis, Structures, Entanglement and Structural Transformation

摘要


雙醯胺雙吡啶配位基含有可與金屬配位的氮與氧原子及不同的-(CH_2)_n-骨架,在配位高分子的製備中扮演重要的角色。此篇報告回顧含雙醯胺雙吡啶配位基配位高分子的製備方法,包括混合配位基的概念。此類化合物的糾纏現象與結構轉換亦將加以探討。

並列摘要


The role of bis-pyridyl-bis-amide (bpba) ligands, which possess various active donor atoms (N and O) and different flexible -(CH_2)_n- skeletons, is significant in the construction of coordination polymers. In this report, preparations of different dimensional networks based on the bpba ligands with or without participation of auxiliary polycarboxylate ligands are described, along with an overview of the entanglement and structural transformation of the bpba-based coordination polymers.

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