Metal powders can be plated to produce composite powders in order to change their surface properties by electroless plating method. But electrolyte instability and various plated proportion often occur. For developing stable and efficient electroless plating technique, we control the composition and proportion of the electrolyte in this investigation expected to get excellent plated composite powders. In this study, we proceed to develop electroless copper plating on tungsten and titanium powders and use ICP-AES and SEM observation on these produced composite powders. The results show that uniform coated W/Cu and Ti/Cu composite powders can be produced when the proportion of plated copper is under 15%.