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高效率RH程序之流力設計及應用於真空氧脫碳反應

Hydrodynamic Design for a High Performance RH-Process and Its Application in Vacuum Oxygen Decarburization

摘要


為配合電氣鋼片、IF鋼、及超深衝性鋼片等極低碳鋼材漸增的需求,於中鋼結合LBE頂底吹轉爐煉鋼,開發高效率RH真空氧脱碳程序,此項工作正積極在進行。對於高效率RH程序之流力設計,本研究透過一系列的水模實驗,探討氣體各種吹射/攪拌方式,以促進鋼液在真空槽-盛鋼桶間的環流速率,上昇管與真空槽內氣-液雙相質傳係數,及程序鋼浴流攪拌混合的效果。於現場160噸處理容量RH真空脫氣設備的實驗,採用多孔吹嘴氣體引導管(Multiple-Nozzles Snorkel),以利氬氣高吹射流量的建議。實驗證實真空氧脫碳反應動力常數自0.08〜0.10min^(-1)提昇到0.15〜0.20min^(-1)水準。經15〜20分鐘真空氧脫碳的處理,鋼液碳含量可以自150〜200 ppm,脫除到20 ppm以下;及自250〜300ppm脫除到20〜30ppm。

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並列摘要


High decarburization efficiency of RH-process has been developed at CSC by combining the LBE converter with steelmaking. Hydrodynamic design for this high performance RH-process was evaluated via a series of water-modelling experiments to maximize the molten-steel circulation between ladle and vacuum vessel, to optimize liquid-gas mass transfer in both up-leg and vacuum vessel, and to improve the bulk-phase mixing. Multiple-nozzles snorkel and higher argon gas flow rate were suggested and adopted to industrial-plant experiments with 160 tons capacity RH degasser. Reaction rate constant for vacuum oxygen decarburization was improved from 0.08-0.10/min to 0.15-0.20/min. The carbon content can be reduced from 150-200 ppm to below 20ppm and from 250-300 ppm to 20-30 ppm in 15-20min treatment, This enables CSC to produce ultra-low carbon steel to supply the increasing demand of electrical steel, interstitial free steel and extra-deep drawing steel, etc.

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