A Zn_(0.48)Cd_(0.52_Se/Zn_(0.24)Cd_(0.18)Mg_(0.58)Se asymmetric coupled quantum well structure was characterized by temperature dependent photoluminescence (PL) in the range of 10-300 K. PL emission dominated by an excitonic recombination behavior was observed. The activation energy was determined by an Arrhenius plot of the integrated PL emission intensity as a function of temperature. The temperature dependencies of the PL energy were analyzed using the Varshni and Bose-Einstein expressions in the temperature range from 10 to 300 K. The parameters that describe the temperature variations and broadening function are evaluated and discussed.