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高性能阻燃合板製造及其膠合品質與熱釋放性質

Manufacturing of High Performance Fire-retardant Plywood and Bonding Quality and Heat Released Properties

摘要


本研究之目的為探討面、底板為紅柳桉及中板為放射松材料,研製四種不同厚度(5,9,12及18 mm)之阻燃合板。各單板首先以阻燃劑A(奈米液態陶瓷阻燃劑)含浸處理後,MUF膠合劑中再混合阻燃劑B(高濃度熱固型膠料阻燃劑),以研製阻燃合板。成板分別進行膠合剪力(Type Ⅱ)、吸濕性、含水率及密度檢定後,次以CNS 14705“建築材料燃燒熱釋放率試驗法-圓錐量熱儀法”,使用Cone Ⅱ圓錐量熱儀,於熱通量50 kW/m2下進行燃燒試驗。四種厚度阻燃合板均可通過CNS 1349規定之TypeⅡ級合板,且阻燃合板膠合剪力僅較對照組者低3.0 %~4.1 %。四種厚度阻燃合板之含水率及吸濕性檢定後分別可通過CNS 11668及CNS 11669合格標準。又,四種厚度阻燃合板分別可通過CNS 14705耐燃3級(5 mm及 9 mm)與耐燃2級(12 mm及18 mm),且處理合板之各項燃燒性能比對照組顯著改善,其減低率分別為180 sec熱釋放率(HRR180)95.5%~97.3 %;總熱釋放量(THR)94.9%~96.9 %;有效燃燒熱(HOC)96.4%~97.7 %及平均質量損失率(MLR)21.6 %~52.9 %。顯見,本研究各處理合板之阻燃效應已獲得大幅改善。

並列摘要


The purpose of this study was to explore four thickness (5, 9, 12, and 18 mm) fire-retardant plywood. Firstly, surface and bottom layer using red lauan and middle layer using radiata pine as raw material impregnated fire-retardant A, and then MUF resin mixed fire-retardant B to manufacture the fire-retardant plywood. Several physical characteristics (bonding shear strength (Type II), hygroscopicity, moisture content, and density) and heat releasing properties of fire-retardant plywood were examined. According to CNS 14705 ”Method of test for heat release rate for building materials - Cone calorimeter method” using Cone II colorimeter heated at 50 kW/m^2 combustion test. The four thickness of fire-retardant plywoods can meet the CNS 1349 of Type II and the bonding shear strength of fire-retardant plywood than control group were only reduced 3.0 %~4.1 %. Also, four thickness fire-retardant plywoods moisture content and hygroscopicity were met CNS 11668 and 11669, respectively. Four thickness fire-retardant plywoods met CNS 14705 fire retardant grade 3 (5 and 9 mm), and grade 2 (12 and 18 mm), respectively. Meanwhile, when compared with the control group reduce the heat release rate(HRR180)were 95.5 %~97.3 %, total heat released(THR)94.9 %~96.9 %,effective heat of combustion(HOC)96.4 %~97.7 %, and average mass loss rate(MLR) 21.6 %~52.9 %, respectively. Obviously, the efficiency of fire-retardant of treated plywoods improved significantly.

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