This study investigates the effect of exposure to various elevated temperatures on the engineering properties of composite alkali activated material manufactured by different dosages of activator, water-solid ratios, amounts of sand and proportions of slag-fly as mixtures. The experimental results show that: (1) The addition of fly ash only causes a slight increase of thermal conductivity. (2) The addition of fly ash can significantly increase the strength of specimen with increase of 40~60% when after exposure to 400℃ temperature. (3) The result of microscopic tests indicate that it has large number of unreactive fly ash particles at room temperature, but the microstructure of alkali activated material becomes denser to enhance the strength of the material exposed to elevated temperature.