The purpose of high light-transmitting/heat-shielding coating is to effectively block the transmission of heat such as infrared rays of sunlight. On the other hand, it can also block the ultraviolet to avoid the furnishings aging or color fading. The coating uses Aerogel and Hollow glass spheres to decrease the coating thermal conductivity, and add modified nano-mica powder to promote the infrared shielding. The results show with the coating thickness of 150 μm, the visible transmittance of the coating is 44.0%, the near-infrared shielding rate is 77.5%, and the thermal conductivity is 0.042 W/m.K. After 40 hours of testing, the light fastness reaches 4-5 and the coating particle size is 342.3 nm. It means that the coating has certain heat barrier properties and storage stability.