Using the airbone LiDAR high-resolution DEM data to identify lineament structure provides an opportunity to generate more comprehensive structural maps. In this study, we use Mt. Xian-Du Landslide area (Hsiaolin Village) in Kaohsiung city and Guguan-Deji area in Central Cross-Island Highway as example to demonstrate how we applied the LiDAR DEM for field investigation. With the use of high-resolution DEM we identified a series of east-northeast to west-southwest trending structures in Mt. Xian-Du Landslide area. During field investigation we recognized characteristics of these structures, they are generally the strike-slip faults, and track its continuity, as well as other structural relationships. In the high- resolution DEM using of Guguan-Deji area, we observed the north-south and northeast-southwest trending structures. However, the structures in this area are complex in nature, and we cannot recognize the nature of structures directly by DEM. Using the high-resolution DEM can enhance the utility of remote sensing for structural mapping since these data sets enable the extraction of detailed information about both local and regional geological structures. However, field checking is always necessary before the structure.