- 期刊
Preparation and Properties of Epoxy-modified Waterborne Polyurethane/polyacrylate Composite Emulsion with the Action of Polmerizable Emulsifier
摘要
With the introduction of glycidyl methacrylate (GMA) and allyloxy hydroxyl propanesulfonic salt (AHPS) to the waterborne polyurethane/polyacylate (WPUA) emulsion, a stable epoxy-modified waterborne polyurethane/polyacylate (EPUAS) composite emulsion with high solid content had been obtained. The structure and morphology were characterized by Fourier transform infrared spectroscopy (FTIR), transmission electron microscope (TEM) and X-ray diffraction (XRD). The GMA content and the AHPS content on properties of the emulsion and films were discussed. The FTIR results showed that GMA and AHPS both reacted with WPUA. A core-shell structure is observed by TEM. The properties of EPUAS emulsion and films were improved by modification.
延伸閱讀
- 呂銘坤、吳雪舫（1980）。Studies on Emulsion Copolymerization of Styrene and Butyl Acrylate with Mixed Emulsifier。化學，(69年2)，25-35。https://doi.org/10.6623/chem.1980007
- Shaffei, K. A., Moustafa, A. B., & Hamed, A. I. (2009). The Emulsion Polymerization of Each of Vinyl Acetate and Butyl Acrylate Monomers Using bis (2-ethylhexyl) Maleate for Improving the Physicomechanical Properties of Paints and Adhesive Films. International Journal of Polymer Science, 2009(), 54-59. https://doi.org/10.1155/2009/731971
- 趙虹宇（2012）。Synthesis, Structure Characterization and Dynamic Properties of an Organic-Inorganic Hybrid Polymer Electrolyte Based on Polyether Epoxy.〔碩士論文，國立中央大學〕。華藝線上圖書館。https://www.airitilibrary.com/Article/Detail?DocID=U0031-1903201314442514
- 王政安（2019）。Preparation and Characterization of Novel Bifunctional Waterborne Polyurethane-Potassium Poly(acrylate) Polymer for Flexible Supercapacitors〔博士論文，國立清華大學〕。華藝線上圖書館。https://www.airitilibrary.com/Article/Detail?DocID=U0016-0206202016121612
- 吳宜哲（2017）。Functionalization of poly(ethylene terephthalate) membrane through coating to epoxylated sulfobetaine copolymers prepare anti-fouling biocompatible material〔碩士論文，中原大學〕。華藝線上圖書館。https://doi.org/10.6840/cycu201700679