The purpose of this study is to explore the relationships between the enrollment ratio of the education (the enrollment ratio of primary education, the enrollment ratio of secondary education, the enrollment ratio of higher education, and the ratio of tree-level education), and human poverty indicators (people not expected to survive to age 40, population without assess to safe water, health services, sanitation, underweight children under age five, per capital income, adult illiteracy rate). By using the Structural Equation Modeling (SEM), the research results show that the relationships between the educational indicators and human poverty indicators are negative significantly in 1997. In addition, the study also uses educational indicators and poverty indicators to discriminate 65 countries into high-poverty, middle-poverty, and low-poverty countries. Due to most of the developing countries' people are under the condition of poverty, the research also points out some problems and reducing poverty strategies for the developing countries.