- 期刊
Preparation of Amorphous Silica from Oil Shale Residue and Surface Modification by Silane Coupling Agent
並列摘要
Two kinds of modified amorphous silica, grafted vinyl trimethoxysilane (AH-171) and N-(n-butyl)-3-aminopropyl trimethoxysilane (DYNASYLAN 1189), were obtained from oil shale residue by the technical process of calcination and activation, alkaline dissolution, homogeneous sedimentation with ethylacetate and modification with silane coupling agents. The number of surface hydroxyl groups, modification degree, the structure and other properties of amorphous silica were investigated by chemical method, infrared analysis, nuclear magnetic resonance analysis, X-ray diffraction and scanning electron microscopy. The results show that amorphous silica treated with coupling agents AH-171 and DYNASYLAN 1189 is characterized by modification degrees of surface hydroxyl groups 93.7% and 71.2% and hydrophobic degrees 98% and 94%, respectively, as well as also by improved dispersion in organic solutions. This work gives a valid method to prepare surface modified amorphous silica from the oil shale residue.
並列關鍵字
無資料延伸閱讀
- 李淑真（2004）。Preparation and Properties of Polyimide(ODA-BSAA)/silica and Polyimide(BAPN-OPDA)/silica Hybrid Materials〔碩士論文，中原大學〕。華藝線上圖書館。https://doi.org/10.6840/cycu200400329
- 李紀平、張俊賢、林唯芳（2003）。Synthesis of Monodisperse Silica Particles。材料科學與工程，35(4)，245-249。https://doi.org/10.6409/JMSE.200312.0245
- 吳東明、高憲明、王家麟（2005）。Mesoporous Silica Used in the Enrichment of Ambient Organic Pollutants。化學，63(3)，353-364。https://doi.org/10.6623/chem.2005029
- 柳佳欣（2010）。Effect of Anion on the Formation of Mesoporous Silica and Synthesis of Metal Modified Hollow Silica Sphere〔碩士論文，國立臺灣大學〕。華藝線上圖書館。https://doi.org/10.6342/NTU.2010.10035
- 陳威廷（2006）。Preparation of Polyimide-silica Composites and Study on Coupling Agent〔碩士論文，國立臺北科技大學〕。華藝線上圖書館。https://www.airitilibrary.com/Article/Detail?DocID=U0006-1407200615080400