This study is to explore the relationship between perceived luxury and customer satisfaction by using both the questionnaire and qualitative interview to the named brand perfume consumers. The empirical analysis shows that the positive relationship between perceived luxury and customer satisfaction was moderated by the trait of vanity. The authors find that the higher the trait of vanity, the stronger the customer perceived luxury associates with customer satisfaction than the lower trait of vanity does. Besides, perceived hedonic and perceived extended-self have significant effects on customer satisfaction. The authors also provide some feasible direction for further research.