Using the definition of asset allocation efficiency and the methodology presented in Wurgler (2000), we estimate the efficiency of capital allocation across the range of the whole country and the state-owned industrial firms through their relating data from 1990 to 2003. We adopt two definitions of absolute financial structure and relative financial structure to depict our country's financial structure. According to the extent to which the financial structure can explain the asset allocation efficiency, we evaluate the relationship between the financial structure and economic structure. Then we present the existing problems.