The purpose of this study is to investigate the influence and relationship among the senior students of high and vocational school students on values and behavioral intention. A total of 450 questionnaires were distributed and 380 responses were collected, giving a return rate of 95%. 30 questionnaires were invalid and 350 questionnaires were valid representing a 92.1% valid response rate. A survey instrument for measuring value and behavioral intention was used to collect data, which were analyzed by using descriptive statistics, internal consistency analysis, one-way ANOVA, t-test, and mediated regression analysis. The main results of this study are as the following: 1. Statistically significant differences were found on value with regard to gender and other four background variables; 2. Some statistically significant differences were found on behavioral intention with regard to gender and other four background variables; 3. The values of the high and vocational school senior students had a mediation effect on their behavioral intention.