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Low‐temperature Sintering of Bi_2O_3‐B_2O_3 Glass Doped Li_2ZnTi_3O_8 ‐ Li_2TiO_3 Ceramic and Its Dielectric Properties

摘要


The effects of Bi_2O_3‐B_2O_3 (BBO) glass addition on phase composition, microstructure and microwave dielectric properties of 0.65Li_2ZnTi_3O_8‐0.35Li_2TiO_3 (LZT) ceramics were investigated in this paper. It was found that a small amount of BBO addition could not only effectively lower the sintering temperatures from 1100 ℃ to 840 ℃, but also reduce the temperature coefficient of resonant frequency (τ_f) and the Q×f value of LZT ceramic. When BBO content exceeded 3 wt%, an unknown phase was detected. Typically, the 0.5 wt% BBO doped LZT ceramic sintered at 840 ℃ for 4 h had good microwave dielectric properties of εr = 26.6, Q×f = 40,683GHz and τ_f = +1.0ppm/℃, it a promising ceramic for LTCC technology application.

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