- 期刊
氯乙烯偏二氯乙烯乳化共聚合之研究
Emulsion Copolymerization of Vinyl Chloride and Vinylidene Chloride
摘要
用自製之氯乙烯與偏二氯乙烯，按其分子六十比四十，加十二醇硫酸酯鈉鹽為乳化劑，過硫酸鈉為活化劑，行乳化共聚合。經實驗，發現乳化劑與活化劑用量多，反應速度快。反應溫度對平均聚合度與反應速度有顯著之影響。轉動速度快，反應稍加速。惟欲求高濃度之乳液成品，則其操作時之乳化狀況，成品之穩定度，及求符合塗佈技術之各項物理性質，尚需繼續探討。
關鍵字
無資料並列摘要
The emulsion copolymerization of vinyl chloride and vinylidene chloride, in mole ratio of 60:40, was carried out using sodium lauryl sulfate as emulsifier and potassium persulfate initiator. The preliminary results showed that conversion increased with the increasing of catalyst and emulsifying agent, but only slightly influencied by the rate of agitation. The mean degree of polymerization was prominently effected by reaction temperature. In order to prepare high resin content latex, further studies should be conducted.
並列關鍵字
無資料延伸閱讀
- 王維義、蘇珍徽（1957）。氯乙烯偏二氯乙烯懸浮共聚合之研究。化學，(46年4)，191-200。https://doi.org/10.6623/chem.1957016
- Li, C. L. (2010). 以非溶劑誘導式相分離法製備聚偏二氟乙烯薄膜及其成膜機制之探討 [doctoral dissertation, National Taiwan University]. Airiti Library. https://doi.org/10.6342/NTU.2010.00104
- 彭俞儒（2020）。利用激發表面電漿波之Otto組態對聚氯乙烯及鄰苯二甲酸二(2-乙基己基)酯之研究〔碩士論文，健行科技大學〕。華藝線上圖書館。https://www.airitilibrary.com/Article/Detail?DocID=U0022-2507202015431600
- 李威儒（2006）。聚偏二氟乙烯接枝聚甲基丙烯酸甲酯之原子轉移自由基合成與其自組裝行為的探討〔碩士論文，淡江大學〕。華藝線上圖書館。https://doi.org/10.6846/TKU.2006.00773
- 呂銘坤、吳雪舫（1980）。Studies on Emulsion Copolymerization of Styrene and Butyl Acrylate with Mixed Emulsifier。化學，(69年2)，25-35。https://doi.org/10.6623/chem.1980007