- 期刊
無機離子交換劑之合成與其在原子能之應用 第二報 矽酸鋯及氫氣化鈰對金屬離子分配係數之研究
Synthesis of Inorganic Ion Exchangers and Their Uses in Atomic Energy II. The Distribution Coefficients of Metal Ions For Inorganic Ion Exchangers of Zirconium Silicate and Hydrous Ceric Oxide
摘要
本研究係依據去年之研究結果，從14種無機離子交換劑中選出新發現及性質優良之兩種交換劑，矽酸鋯及氫氧化鈰；又按金屬之原子價選出20多種金屬鹽類作該兩種交換劑對此等金屬離子交換封配係數之測定，以觀察此兩種交換劑作實際應用金屬離子分離之可能性。本研究分配係數測定之分析係完全採用配位滴定法(chelatometric titration method)，並根據試驗結果使用矽酸鋯交換劑作Th與Sm之分離及使用氫氧化鈰交換劑作Ca與Sr之分離，結果十分良好。
關鍵字
無資料並列摘要
The distribution coefficients of metal ions for two inorganic ion exchangers of zirconium silicate and hydrous ceric oxide which were selected from 14 synthetic ion exchangers were investigated. The possibilities of using these two ion exchangers to exchange metallic ions were predicted from the distribution coefficients. Chelatometric titration method was used for measuring the distribution coefficients. A method has been developed for separating thorium from samarium and calcium from strontium with zirconium silicate and hydrous eerie oxide as ion exchanger, respectively. Both gave excellent results.
並列關鍵字
無資料延伸閱讀
- 譚盪波、孫樸、陳國元（1965）。無機離子交換劑之合成與其在原子能之應用 第一報 無機離子交換劑之合成及性質。化學，(54年1&2)，33-38。https://doi.org/10.6623/chem.1965006
- Shih, B. W. (2020). 原子層沉積之金屬氧化物及高分子/金屬氧化物超晶格複合材料熱電性質及氣體滲透率研究 [doctoral dissertation, National Taiwan University]. Airiti Library. https://doi.org/10.6342/NTU202000015
- Wei, H. C. (2016). 藉同步輻射及中子技術研究釩摻雜之磷酸鋰鐵在鋰離子電池中的化學與晶體結構相變行為 [doctoral dissertation, National Tsing Hua University]. Airiti Library. https://www.airitilibrary.com/Article/Detail?DocID=U0016-2309201616093125
- 劉子郡（2021）。利用原子層級模擬探討碳化矽與矽碳氧負極材料之鋰化、鈉化、鉀化機制〔碩士論文，國立臺灣大學〕。華藝線上圖書館。https://doi.org/10.6342/NTU202104414
- Ezzeldin, H. A., Apblett, A., & Foutch, G. L. (2010). Synthesis and Properties of Anion Exchangers Derived from Chloromethyl Styrene Codivinylbenzene and Their Use in Water Treatment. International Journal of Polymer Science, 2010(), 215-223. https://doi.org/10.1155/2010/684051