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  • 期刊

甲醇和異丙醇與籠型三價鈷配位化合物之光化學反應

Photochemical Reactions of Methanol or Isopropanol and Cage-like Co(III) Complexes

摘要


籠型三價鈷配位化合物Co(tpen)^(3+)及Co(tptn)^(3+)在水溶液中具有光敏催化的作用,可以將醇類氧化成醛類或酮類,可是光產率不高,約在10^(-2)到10^(-3)之間。

關鍵字

光催化反應

並列摘要


It is found that cage-like Co(III) complexes, Co(tpen)^(3+) and Co(tptn)^(3+), can undergo photocatalytical reactions with methanol and isopropanol to form formaldehyde and acetone, respectively. The quantum yields were found to be between 10^(-2) to 10^(-3).

並列關鍵字

photosensitization

延伸閱讀