- 期刊
Sulfur-Assisted Chloride and Triphenylphosphine Dissociation of Palladium(II) Complex [Pd(PPh_3)_2(ŋ^1-SCOPh)(Cl)]. X-ray Structure of [Pd(PPh_3)_2(ŋ ^1-SCOPh)(Cl)]
硫－輔助鈀金屬錯合物-[Pd(PPh_3)_2(η^1-SCOPh) (C1)]中氯離子與三苯基膦解離：錯合物[Pd(PPh_3)_2(η^1-SCOP的(C1)]的晶體構造
並列摘要
Treatment of Pd(PPh_3)_4 with phenylchlorothiocarbonate, PhOC(=S)C1, in dichloromethane at -20 produces the oxidative addition palladium complex [Pd(PPh_3)_2(ŋ^1-SCOPh)(C1)], 2 with releasing two triphenylphosphine ligands. The ^(31)P{^1H} NMR spectra of complex 2 shows the dissociation of either the chloride or the triphenylphosphine ligand to form complex [Pd(PPh_3)_2(ŋ^2-SCOPh)][Cl], 3 or the dipalladium complex [Pd(PPh_3)C1]_2(ŋ^2-SCOPh)_2, 4. Complex 2 is characterized by X-ray diffraction analysis.
參考文獻
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