百葉窗靜電集塵器之開發與電暈放電產生奈米微粒現象之探討

Development of the louver electrostatic precipitator and the characteristics of particle generation by corona discharge

林志威(Chih-Wei Lin)

指導教授 ： 陳志傑

國立臺灣大學/公共衛生學院/職業醫學與工業衛生研究所/博士(2012年)

https://doi.org/10.6342/NTU.2012.02039

摘要

空調系統能夠創造舒適的室內環境，但是須要耗費大量能源，使用自然通風則會讓外界污染物進入室內。本研究研發一百葉窗型靜電除塵器，能夠在使用自然通風時同時去除空氣中的微粒。並且探討靜電集塵器轉變成奈米微粒產生器之現象，找出影響此現象之參數，設計出一以電暈放電為基礎之奈米微粒產生器。

實驗中使用板線型靜電集塵器，在測試不同實驗參數下量測靜電集塵器的穿透率、能量品質、臭氧濃度以及產生微粒分布。實驗參數包括收集板角度、收集板長度、放電極位置、電場強度、電流強度、氣流風速、溫度、放電極直徑、放電極材質、收集板間距離以及挑戰氣膠濃度與大小。同時也針對產生微粒的外觀以及成分進行分析。

實驗結果顯示收集板角度增加會減少收集板與放電極間的距離，風速與電場分布也隨之改變。過高的電場強度會大幅降低能量品質。增加氣流溫度、降低挑戰氣膠濃度降低以及增加放電極直徑可降低靜電集塵器產生的微粒濃度。在特定的電場強度以及風速下，有最高的微粒濃度。使用過後的放電極表面有氧化現象，此氧化層會影響微粒產生穩定度，使用金當做電極則可穩定產生。

百葉窗型靜電集塵器可有效阻檔進入室內之輻射熱且同時去除微粒，兼顧自然通風以及空調系統之優點。靜電集塵器除了能夠收集微粒，同時會產生奈米微粒。根據此現象研發之電暈放電奈米微粒產生器具有反應時間短、設備簡單以及可改變濃度等優點，產生的微粒大小為5-40 nm，眾數約在12 nm。

關鍵字

電暈放電 ； 靜電集塵器 ； 奈米微粒 ； 百葉窗 ； 微粒產生器

並列摘要

An air conditioner is used to increase the occupants’ comfort by adjusting the indoor air temperature, but it is a major part of energy consumption. We can achieve equivalent or superior results by using general ventilation but drawbacks may include the incursion of outdoor air pollutants and an increase in radiant energy from sunlight into the home. This study designs a low-cost, practical, louver-window-type, electrostatic precipitator that can reduce pollutants entering the indoor space and shade the indoor area, while permitting increased ventilation in a home or small office environment. We also demonstrated that an electrostatic precipitator, originally designed for dust collection, could become an efficient nanoparticle generator under specific operating conditions. This unique feature was utilized in the present study to develop a nanoparticle generator based on corona discharge.

A lab-scale, adjustable, wire-plate positive louver ESP and a wire-plate corona discharger were built for measuring particle penetration, energy quality, ozone concentration and particle emission. Environmental contaminants were removed by HEPA filter, active charcoal and silica gel. Gold, tungsten, molybdenum, and stainless steel were used as the electrode to study the material dependency. Gas temperature was controlled by a feedback heater. A positive direct current power supply was employed to energize the corona discharger. A scanning mobility particle sizer with a nano differential mobility analyzer was employed to measure the aerosol number concentration and size distribution. Ozone concentration was monitored by using an ozone analyzer. The sampling locations of SMPS and ozone analyzer were 20 and 15 cm downstream the corona discharger, respectively. The major operating parameters included louver angle, electrode diameter, electrode spacing, electrode material, air velocity, air temperature, applied voltage and current.

The results showed that the louver adjustment significantly affected the ESP performance. The discharge wire should be positioned in the middle to provide optimal ESP performance, although moving around the electrode did not significantly change the energy consumption and ozone generation. The collection plates with excessive length were proven to be ineffective. The wire-to-plate distance decreased with increasing louver angle. The louver adjustments resulted in changes of the effective collection area, electric field strength and air velocity. The field strength should be as low as possible to obtain a high energy quality index. For a given energy consumption, the energy quality index was not significantly affected by the louver angle. This phenomenon was due to a trade-off between the electric field strength and the effective collection area. Therefore, all aerosol penetration curves showed within a narrow band.

The air temperature appeared to have a strong effect on ESP nanoparticle generation. At temperature above 37°C and flow rate below 9 L/min, the nanoparticle penetration of ESP exceeded 100%, indicating that the ESP was generating aerosol particles. Sputtering on the corona discharger appeared to be the key mechanism of aerosol generation. Particles were generated as soon as the ESP was on set. The ozone concentration increased with increasing corona current. The ESP reached a maximum number concentration at the electric field strength of 4.8 kv/cm when the air flow and temperature were fixed at 6 L/min and 40°C, respectively. The particle size ranged from 5 to 40 nm. Elementary components of the discharge wire were detected on the filter samples collected downstream the ESP and ground plates, indicating that nanoparticles were generated from the discharge wire. The ESP transit to a nanoparticle generator when it could not efficiently capture the particles generated from itself.

The maximum aerosol concentration occurred when the electric field strength was around 8.2, 9.8, and 11.2 kV for electrode diameter of 0.1, 0.2 and 0.3 mm, respectively. The smaller discharge electrode diameter generated more aerosol particles, but lower ozone concentration when compared to larger electrode diameter. The differences in aerosol concentration due to the change of electric field strength decreased with increasing electrode diameter, because the mean kinetic energy was more uniform in the larger electrode. Electrode materials did not affect the I-V curve but the aerosol generation rate and the ozone concentration were clearly material-dependent. Gold was chosen as the discharge electrode because of stable and high sputtering yield.

並列關鍵字

corona discharge ； electric field strength ； nanoparticle ； louver ； particle generator

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