隔熱膠膜之光學性質

Optical Properties of Heat Insulation Films

林家德(Chia-Te Lin)

指導教授 ： 林清彬

淡江大學/工學院/機械與機電工程學系碩士班/碩士(2007年)

https://doi.org/10.6846/TKU.2007.00120

摘要

本研究係以自行合成之有機染料，加入六硼化鑭和氧化銻錫兩種阻擋近紅外線材料，與UV膠混煉後進行曝光製造出一隔熱膠膜，並針對六硼化鑭進行不同溫度燒結製造出來的隔熱膜分別做一光譜分析，及進行飛散及耐久測試。實驗合成出之染料其良好之耐熱性質適合應用在隔熱膠膜上，有助於隔熱膠膜之耐久性質；六硼化鑭經高溫燒結會從原來LaB6相轉變為LaB3O6相，隨著燒結溫度升高造成表面氧化情形更加明顯，顏色由原來深變為淡。未經燒結之六硼化鑭搭配染料，及摻入氧化銻錫的情形之下，製作出隔熱膠膜可以在近紅外線阻擋約55%的穿透；隔熱膠膜經飛散測試之後證明安全毋庸置疑；隔熱膠膜經環測、剝離強度試驗之後，觀察玻璃表面未發現有殘膠之情形。

關鍵字

隔熱膠膜 ； 六硼化鑭 ； 光學性質 ； 耐久性質

並列摘要

In this thesis, self-made synthetic organic dyes and added LaB6 and antimony tin oxide two blocked near infrared materials, then mixing with UV resin and exposure to manufacture a heat insulation film, and against LaB6 at different sintering temperature manufacturing the heat insulation film were doing an spectrum analysis, and for glass scattering and durability testing. Experimental synthesized dyes its good heat resistant properties suitable for heat insulation films, and contribute to the heat insulation films’ durable properties; LaB6 sintered at high temperature from the original phase (LaB6 phase) transformation to LaB3O6 phase, With the sintering temperature arise, oxidation of the surface caused significantly more obviously, the original colors deep into desalination. Without sintering's LaB6 mix dyes, and added antimony tin oxide, heat insulation films produced in the near-infrared blocked about 55%. After glass scattering testing, the heat insulation films proved beyond doubt safety. The heat insulation films measured by environment testing、peel strength testing, observation of the glass surface is not aware of any residues of cases.

並列關鍵字

Heat Insulation Films ； Lanthanum hexboride ； Optical Properties ； Durable Properties

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