以含多硼衍生物修飾玻璃表面及其應用

The Installation of Multiple Boron containing Compounds onto the Glass Surface and its Applications

潘冠霖(Kuan-Lin Pan)

指導教授 ： 潘伯申

淡江大學/理學院/化學學系碩士班/碩士(2022年)

https://doi.org/10.6846/TKU.2022.00606

摘要

利用Ugi 合成含硼胜肽化合物(I)
使用Ugi-4CR 反應成功合成出含硼類肽化合物，將藉由去硼酯與去Boc
保護應用在材料上 (Scheme 1)。
硼酯和Boc 去保護(II)
成功在含Boc 保護基的化合物去硼酯保護和在含硼酸情況下成功去Boc
保護基 (Scheme 2)。
玻璃表面修飾硼酸(III)
藉由DAHMI 與硼酸結合會發出藍色螢光和測量玻璃之Surface zeta
potential 來鑑定硼酸是否修飾在玻璃上 (Scheme 3)。

關鍵字

Ugi 多組成 ； 硼化合物 ； surface zeta potential

並列摘要

Ugi Synthesis of boron-containing peptides (I)
The boron-containing peptide compound (Scheme 1) was
successfully synthesized using the Ugi-4CR reaction, and deprotection
of boronate ester and Boc to use in materials.
Deprotection of boronate ester and Boc (II)
Successfully deboronated ester protection in compounds containing Boc protecting groups and successfully removed Boc
protecting groups in the presence of boronic acids (Scheme 2).
Glass Surface Modified Boronic Acid (III)
The combination of DAHMI and boronic acid will emit
fluorescence and measuring the Surface zeta potential of the glass to
identify whether the boronic acid is modified on the glass (Scheme 3).

並列關鍵字

Ugi Multicomponent Reaction ； Boron compound ； surface zeta potential

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