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  • 學位論文

高分子材料控制OCB液晶盒的預傾角及光電特性研究

Electro-Optical Characteristics of a OCB Liquid Crystal Display with Polymer Controlled Pretilt Angle

指導教授 : 陳殿榮
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摘要


本文研究高分子調變液晶配向之預傾角。首先使用三種高分子單體,分別為單體A,單體C及單體A混合單體C,摻雜入液晶E7形成混合物,將混合物注入至Homogeneous-cell內,外加固化電壓Vuv=10V時,照射UV光60分鐘,使高分子聚合,藉由光穿透率量測、響應時間量測、接觸角量測及SEM量測,探討高分子單體對液晶排列的效應。 其次利用單體A混合單體C與液晶的混合物注入πcell,在照射UV光同時外加不同電壓,使配向膜表面形成高分子網(Polymer network)的結構。在無施加電壓下,液晶初始穩定在splay、twist或bend排列,以偏光顯微鏡圖、穿透率量測及視角量測進行光電特性分析,且利用Dimos軟體模擬π-cell初始狀態的預傾角。

關鍵字

π-cell 預傾角 單體 高分子

並列摘要


In this study, we used photo-polymer to control the pretilt angle in a LCD cell. First, we added monomer A, monomer C, and a mixture of monomers A and C to liquid crystal E7, respectively. The mixture of monomers and liquid crystal was filled into a homogeneous cell. The photo-polymerization proceeded in the homogeneous cell with an ac electric field applied to it. We varied the UV exposure time and investigated the electro-optical effect on LC cell. Secondly, liquid crystal E7 doped with monomers A and C was filled into a π-cell. The LC molecular alignment and electro-optical characteristics in the cells were investigated by polarizing optical microscopy, voltage dependent transmission and viewing angle. We verified the experimental result by simulated analysis.

並列關鍵字

π-cell pretilt angle monomer polymer

參考文獻


[1] E. C. Peter, M. Petro, F. Svec, J. M. J. Frechet, “Molded Rigid Polymer Monoliths as Separation Media for Capillary Electrochromatography. 1. Fine Control of Porous Properties and Surface Chemistry”, Fréchet, Anal. Chem., vol. 70, 1998, pp. 2288-2295.
[2] C. Yu, M.C. Xu, F. Svec and J.M.J. Frechet, “ Preparation of monolithic polymers with controlled porous properties for microfluidic chip applications using photoinitiated free-radical polymerization”, J. Polym. Sci., A, vol. 40, 2002, pp. 755–769.
[3] T. Rohr, E.F. Hilder, J.J. Donovan, F. Svec and J.M.J. Fréchet, “Photografting and the control of surface chemistry in three-dimensional porous polymer monoliths”, Macromolecules, vol. 36, 2003, pp. 1677-1684.
[4] D. W. Berreman, “Liquid‐crystal twist cell dynamics with backflow”, J. Appl. Phys., vol. 46, 1975, pp. 3746.
[5] C. Z. van Doorn, “Dynamic behavior of twisted nematic liquid‐crystal layers in switched fields”, J. Appl. Phys., vol. 46, 1975, pp. 3738.

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