本文研究高分子調變液晶配向之預傾角。首先使用三種高分子單體,分別為單體A,單體C及單體A混合單體C,摻雜入液晶E7形成混合物,將混合物注入至Homogeneous-cell內,外加固化電壓Vuv=10V時,照射UV光60分鐘,使高分子聚合,藉由光穿透率量測、響應時間量測、接觸角量測及SEM量測,探討高分子單體對液晶排列的效應。 其次利用單體A混合單體C與液晶的混合物注入πcell,在照射UV光同時外加不同電壓,使配向膜表面形成高分子網(Polymer network)的結構。在無施加電壓下,液晶初始穩定在splay、twist或bend排列,以偏光顯微鏡圖、穿透率量測及視角量測進行光電特性分析,且利用Dimos軟體模擬π-cell初始狀態的預傾角。
In this study, we used photo-polymer to control the pretilt angle in a LCD cell. First, we added monomer A, monomer C, and a mixture of monomers A and C to liquid crystal E7, respectively. The mixture of monomers and liquid crystal was filled into a homogeneous cell. The photo-polymerization proceeded in the homogeneous cell with an ac electric field applied to it. We varied the UV exposure time and investigated the electro-optical effect on LC cell. Secondly, liquid crystal E7 doped with monomers A and C was filled into a π-cell. The LC molecular alignment and electro-optical characteristics in the cells were investigated by polarizing optical microscopy, voltage dependent transmission and viewing angle. We verified the experimental result by simulated analysis.