In this work, we propose and experimentally demonstrated a multi-service signals generation module based on polarization modulator for RoF communication system. With the assistance of a polarization beam splitter, the pol-x and pol-y sidebands of optical polarization modulated multi-service signals can be separated colorlessly to achieve optical double/quadruple frequency. 3-band services are integrated and delivered simultaneously. After transmitting over 25 km single mode fiber, three band signals include OFDM and OOK are successfully achieved the qualities of radio-over-fiber communication.