The research will explore the physical attractiveness and the effect which will affect users’ willing. By the advertisement on Facebook, we can find out the users’ advertising attitude and know the app brand of the mobile facility. It can impulse the users’ usage intention. The research uses 2X2 experimental method. It divides the common spokesman physical attractiveness into two groups, high physical attractiveness and medium physical attractiveness. Also, the apps are divided into shopping group and games group. By using 2X2 for groups. It assigns the experiments to four groups by random. After seeing the advertisement on Facebook, the experiments conduct the surveys. The result of the surveys provides the suggesting on marketing advertisement promotion for marketing managers.