氫鍵維持有機-鈮鎢氧化物複合材料之研究

有機物嵌入無機氧化層形成之有機無機複合物，是材料領域的熱門研究對象，本論文中也致力於研究以氫鍵維持層狀結構的新型材料與其結構穩定因子，發現苯二胺的三種異構物與HNbWO6混合反應後，分子結構與水分子的水合作用，可能影響插層反應的主要因子只有間苯二胺能插入HNbWO6層狀結構之中。另外，研究中也首次將質子化的香豆素1（coumarin 1）插層於HNbWO6的結構之中，香豆素為具有螢光特性的雷射染料分子，希望未來香豆素1及HNbWO6的錯合物，能應用於電致變色的材料上。

關鍵字

層狀無機氧化物； HNbWO6 ；間苯二胺；香豆素1 ；插層反應

並列摘要

Organic molecule intercalated into the inorganic oxide attracts wide attention to prepare novel organic-inorganic composite. In this work, research are focusing on synthesis of hydrogen bond supported organic-inorganic composites and revealing the structural stabilization factors. The layered HNbWO6 compound ion-exchanges with ortho-, meta- and para- phenylenediamine individually. Purely meta- phenylenediamine - HNbWO6 composite can be found in aqueous system. Experiment results show the solvation of organic molecule that may play important role for intercalation reaction. Protonated coumain-1 organic molecule is successfully intercalated into layered HNbWO6 structure. The luminescence property of coumain-1 indicates the potential application of coumarin-1- HNbWO6 composite in electrochromic device.