The purpose of the present study was to discuss the effect of single pass and multi-pass (double and triple pass) tungsten inert gas welding on microstructure, microhardness and corrosion behavior of Ti–6Al–4V titanium alloy. Microstructures of the weldments were investigated using optical microscopy, scanning electron microscopy, energy dispersive spectroscopy, electron probe x-ray microanalyzer and X-ray diffraction analysis. The results showed the Widmanstatten structure was clearly visible in the weld metal. The microstructure revealed a fusion zone presents an acicular martensitic α phase, interlamellar β phase and martensite needles α’ phase. Microhardness values of weld metal and HAZ made under multi-pass were lower than that made under single pass welding. Electrochemical tests indicated that the corrosion resistance could be improved by multi-pass welding.