Because Taiwan is a typical island climate with high temperature and humidity, the corrosion rate of steel is an important factor when engineer predict the service life of steel structures. This objective of this research is to study the effect of Corrosion rate of Unpainted Structural Steel in different degradation conditions. Degradation conditions include immersing the steel in different pH solutions (pH=5, 7, 9, 11, 13), immersing in sea water, exposure in salt spray condition, and exposure in coastal environmental. The corrosion rate is mainly determined by the DC polarization test after steel in different degradation conditions. And the result will be provided as a reference for steel structure design.