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研究生: 馬逸倫
Ma, I-Lun
論文名稱: 適用於發光二極體導電擴散層之石墨烯材料特性研究
Light-Emitting Diodes with Graphene Film as a Transparent Conducting Electrode
指導教授: 胡淑芬
Hu, Shu-Fen
學位類別: 碩士
Master
系所名稱: 物理學系
Department of Physics
論文出版年: 2016
畢業學年度: 104
語文別: 中文
論文頁數: 117
中文關鍵詞: 石墨烯發光二極體氧化鎳
英文關鍵詞: Graphene, light-emitting-diode, NiOx
DOI URL: https://doi.org/10.6345/NTNU202204748
論文種類: 學術論文
相關次數: 點閱:78下載:0
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  • 石墨烯是一種由碳原子六角形陣列的二維碳材料,其具有卓越的特性,如低片電阻、高穿透度、機械與熱特性等,被認為是未來優良之透明導電電極能夠運用於許多光電子元件上。
    本實驗中,吾等將化學氣相沉積生產之石墨烯運用於發光二極體元件之p-GaN上作為透明導電電流擴散層。化學氣相沉積5 sccm甲烷、10 sccm氫氣與100 ~ 500 sccm氬氣濃度混和於攝氏900 ℃沉積石墨烯薄膜,接續運用奈米轉印技術將石墨稀轉印至發光二極體元件之p-GaN上。為了減少石墨烯與p-GaN界面之間蕭特基位能障,在p-GaN表面先沉積厚度為3奈米之鎳奈米層(Ni thin film),緊接著將樣品放置於含氧氣體中以攝氏400℃進行熱退火3分鐘,使其鎳奈米層轉換成氧化鎳(NiO),後續將石墨烯轉印於氧化鎳上再做一次熱退火使石墨烯與NiO/ p-GaN緊密接合,以降低石墨烯與p-GaN之間之蕭特基位能障進而形成歐姆接觸。最後使用圓形傳輸線模型(CTLM)進行電性量測。

    Graphene is a two-dimensional carbon material which consists of hexagonal array of carbon atoms, and offers exceptional characteristics such as high transparency, low sheet resistance, suppleness, etc. In this study, we show that chemical vapor deposition grown graphene on copper foil and transfer it on p-GaN as light-emitting-devices transparent conducting electrode. To decrease Schottky barrier between graphene and p-GaN interface, we deposit Ni nanolayer on p-GaN substract as a buffer layer between graphene and p-GaN. After deposited 3 nm thickness nickel (Ni thin film) on p-GaN surface, followed by placing the sample in an oxygen-containing gas to 400°C thermal annealing for 3 minutes, so that the nickel layer is converted into nano nickel oxide (NiOx) dots. NiOx dots haave high transparency at blue light and UV light region. Follow the graphene transferred to do a thermal anneal make graphene with NiO / p-GaN close contact, in order to reduce the Schottky barrier between graphene and the p-GaN thus forming an ohmic contact on nickel oxide. Finally, using a circular transmission line model (CTLM) for electrical resistance measurements.

    致謝 2 摘要 4 圖目錄 9 表目錄 14 第一章 緒論 15 1.1 研究動機 15 1.2 石墨烯之起源 17 1.3 石墨烯之製備方式 20 1.4 石墨烯基本特性 26 1.4.1 石墨烯電子特性與能帶特性 26 1.4.2 石墨烯光學特性 28 1.5發光二極體介紹與原理 31 1.5.1 發光二極體之原理 31 1.5.2 氮化物發光二極體結構 33 1.6 石墨烯運用於發光二極體 36 1.6.1 電流擴散層之導電薄膜分析 36 1.6.2 導電薄膜材料歐姆接觸 38 1.7 文獻回顧 41 1.7.1期刊回顧 41 1.7.2專利回顧 57 第二章 實驗儀器介紹與樣品製備流程 60 2.1實驗準備與預處理 60 2.2實驗樣品製程 62 2.3轉印步驟 67 2.3.1 PDMS 68 2.3.2 PMMA 70 2.3.3 TRT 72 2.4氧化鎳緩衝層材料實驗 74 2.5石墨烯電流擴散層與發光二極體 74 2.6量測儀器介紹 75 第三章 實驗結果與討論 79 3.1製備石墨烯實驗結果與特性量測 79 3.1.1銅箔預處理差異SEM圖分析 79 3.1.2混和氬氣氣體流量SEM與拉曼圖譜分析 81 3.1.4最佳氬氣氣體流量透光率分析 86 3.1.5最佳氬氣氣體流量片電阻分析 87 3.2氧化鎳緩衝層製程 89 3.2.1不同厚度鎳金屬氧化之EDS分析 89 3.2.2不同厚度鎳金屬氧化之XPS分析 90 3.2.3最佳厚度鎳金屬氧化之穿透度分析 92 3.2.4最佳氧化鎳材料SEM-TEM分析 93 3.3石墨烯電流擴散層組合發光二極體之實驗結果 95 3.3.1轉印後相異退火溫度分析 95 3.3.2轉印後相異退火溫度IV曲線 97 3.3.3最佳退火溫度SIMS分析 98 3.3.4最佳退火溫度TEM量測 100 3.3.5最佳退火溫度CTLM電性量測 101 第四章 結論 105 參考文獻 106

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