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研究生： 葛敬
Ko, Ching
論文名稱： 兩性分散劑的合成以及對於氧化石墨烯砂漿性質的影響
指導教授： 許貫中
學位類別： 碩士
Master
系所名稱： 化學系
Department of Chemistry
論文出版年： 2019
畢業學年度： 107
語文別： 中文
論文頁數： 101
中文關鍵詞： 氧化石墨烯 、兩性離子型 、磺酸系 、砂漿
英文關鍵詞： graphene oxide, amphoteric, sulfonic, mortar
DOI URL： http://doi.org/10.6345/NTNU201900246
論文種類： 學術論文
相關次數： 點閱：69  下載：0 
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    • 摘要 ii Abstract iii 目次 iv 圖次 viii 表次 xii 第一章緒論 1 1-1研究背景 1 1-2研究動機 1 第二章 文獻回顧 4 2-1石墨烯簡介 4 2-2氧化石墨烯簡介 10 2-3高分子界面活性劑與分散機制 13 2-3-1靜電排斥穩定理論 15 2-3-2立體障礙效應 18 2-4水泥 20 2-4-1卜特蘭水泥 20 2-4-2水泥之水化 20 2-4-3氧化石墨烯催化水泥水化反應 22 2-5氧化石墨烯分散在水泥漿體中的機制與困境 25 2-6添加與分散氧化石墨烯水泥砂漿文獻彙整 28 第三章 實驗流程與方法 29 3-1實驗流程 29 3-2實驗藥品與儀器 31 3-2-1藥品 31 3-2-2實驗設備 34 3-3實驗方法 35 3-3-1氧化石墨烯的製備 35 3-3-2PSA之合成 35 3-4結構鑑定與分析 37 3-4-1FT-IR光譜儀 37 3-4-21H-NMR光譜儀 37 3-4-3凝膠滲透層析儀 37 3-5分散劑在氧化石墨烯孔隙溶液之分散性測試 39 3-5-1沉降實驗 39 3-5-2黏度量測 39 3-5-3界達電位量測 39 3-5-4粒徑分布量測 40 3-6添加PSA/GO的水泥漿性質分析 40 3-6-1水泥漿體之拌製 40 3-6-2 X-ray粉末繞射儀 41 3-6-3熱示差掃描分析儀 41 3-6-4掃描式電子顯微鏡 42 3-7添加PSA/GO的水泥砂漿性質分析 42 3-7-1水泥砂漿之拌製 42 3-7-2抗壓強度測試 45 3-7-3抗彎強度測試 45 3-7-4電阻率量測 46 第四章 結果與討論 47 4-1氧化石墨烯之結構鑑定 47 4-1-1氧化石墨烯IR光譜 47 4-1-2氧化石墨烯拉曼光譜 48 4-1-3氧化石墨烯粒徑分布 50 4-1-4氧化石墨烯界達電位 51 4-1-5氧化石墨烯微觀結構 53 4-2 分散劑之結構鑑定 54 4-2-1分散劑 IR光譜分析 54 4-2-2PSA 1H-NMR光譜分析 56 4-2-3PSA之分子量 58 4-3不同分散劑對GO沉降體積的影響 61 4-4不同分散劑對GO的粒徑分布影響 63 4-5不同分散劑對GO的界達電位影響 66 4-6不同分散劑對GO的黏度影響 67 4-7GO水泥漿微結構分析 68 4-8GO水泥漿XRD分析 72 4-9GO水泥漿DSC分析 75 4-10PSA/GO對砂漿抗壓強度的影響 78 4-11PSA/GO對砂漿抗彎強度的影響 83 4-12PSA/GO對砂漿電阻率的影響 88 第五章結論 91 參考文獻 93

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