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研究生: 蕭佳安
Hsiao, Chia-An
論文名稱: 電鍍鋅鋼板無鉻抗蝕皮膜與電化學阻抗行為研究
A Study on Electroplating Zinc Plate Coated by Chromium-free Anti-corrosive Painting and Behavior of Electrochemical Impedance
指導教授: 呂家榮
Lu, Chia-Jung
學位類別: 碩士
Master
系所名稱: 化學系
Department of Chemistry
論文出版年: 2020
畢業學年度: 108
語文別: 中文
論文頁數: 76
中文關鍵詞: 抗指紋塗料溶膠-凝膠法電鍍鋅鋼板電化學阻抗譜
英文關鍵詞: anti-fingerprint coating, sol-gel method, electroplating zinc, electrochemical impedance spectroscopy
DOI URL: http://doi.org/10.6345/NTNU202000876
論文種類: 學術論文
相關次數: 點閱:67下載:0
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  • 中文摘要 II ABSTRACT III 目錄 IV 表目錄 VIII 圖目錄 IX 第一章 緒論 1 1.1 研究背景 1 1.2 鋼鐵材料及其保護 2 1.2.1 鋼鐵的腐蝕 2 1.2.2 腐蝕保護 3 1.3 鍍鋅鋼板及其表面處理 5 1.3.1鍍鋅種類 5 1.3.2 塗油 6 1.3.3 鉻酸鹽鈍化處理 6 1.3.4 磷酸鹽鈍化處理 7 1.3.5 抗指紋塗料 8 1.4 溶膠-凝膠法 9 1.4.1 水解反應 9 1.4.2 縮合反應 11 1.4.3 陳置 13 1.4.4 乾燥 13 1.4.5 溶膠-凝膠法製備皮膜 13 1.5 鋼板表面腐蝕及分析方法 15 1.5.1 鹽霧試驗 15 1.5.2 電化學阻抗譜 18 1.5.3 掃描式電子顯微鏡 21 1.5.4 能量色散X射線譜 23 1.5.5 動態光散射粒徑分析儀 24 第二章 實驗部分 25 2.1 實驗藥品與儀器 25 2.1.1實驗藥品 25 2.1.2實驗器材 25 2.1.3 儀器設備 26 2.2 溶膠-凝膠製備 31 2.2.1 E配方溶液製備 31 2.2.2 A182配方溶液製備 32 2.3 抗指紋皮膜試片製作 33 2.3.1 電化學實驗試片製作 33 2.3.2 皮膜表面結構觀察 34 2.3.3 橫截面結構觀察 34 2.4 電化學阻抗實驗裝置介紹 34 2.4.1 第一代量測裝置 35 2.4.2 第二代量測裝置 36 第三章 結果與討論 38 3.1 溶膠-凝膠法 38 3.1.1 E配方討論 38 3.1.2 A182配方討論 43 3.2 鋼板表面薄膜之電化學測量 47 3.2.1 第一代裝置數據討論 47 3.2.2 第二代裝置再現性測試 50 3.2.3 不同樣品阻抗差異 52 3.3 壓克力樹脂性能探討 54 3.3.1 不同烘烤溫度 55 3.3.2 不同樹脂厚度 56 3.4 不同製程的抗指紋鋼板表面結構比較 59 3.4.1 鋼板皮膜外觀 59 3.4.2 微結構觀察與成分分析 60 3.4.3 抗指紋皮膜厚度分析 63 3.4.4 抗蝕性分析比較 69 第四章 結果與討論 72 參考文獻 73

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